Tetrabenzo-Chichibabin's hydrocarbons: substituent effects and unusual thermochromic and thermomagnetic behaviours

Literature Information

Publication Date 2018-02-12
DOI 10.1039/C8CC00378E
Impact Factor 6.222
Authors

Chuanling Jiang, Yawen Bang, Xinhao Wang, Xuefeng Lu, Zhenglong Lim, Haipeng Wei, Samir El-Hankari, Jishan Wu, Zebing Zeng


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Abstract

Open-shell π-conjugated compounds have recently received intense attention due to their unique properties and promising applications in materials science. However, the experiments on how the substituents affect their chemical bonding and structural motif remain less addressed. In this work, a series of tetrabenzo-Chichibabin's hydrocarbon (TBC) derivatives substituted by different electron-donating or -withdrawing groups at the termini were synthesized. The substituent effect was studied via X-ray crystallographic analysis. The strong electron-donating dimethylamino-group substituted TBC derivative underwent simultaneous oxidation to give two cyanine-like moieties at the termini. More interestingly, it exhibited unusual thermochromic and thermomagnetic behaviours.

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