The amplified electrochemiluminescence response signal promoted by the Ir(iii)-containing polymer complex
Literature Information
Publication Date
2018-04-07
DOI
10.1039/C8AN00426A
Impact Factor
4.616
Authors
Yayun Fang, Ziyu Wang, Yang Li, Yiwu Quan, Yixiang Cheng
View Original
Abstract
A novel Ir(III)-containing polymer complex (P2) as an electrochemiluminescence (ECL) emitter was prepared by the coordination reaction of the N-containing bidentate ligand (–CHN–CH2–CH2–NCH–) in the conjugated polymer P1 with [Ir2(2-ppy)4(μ-Cl)2] (M3). Despite a rather low Ir(III) content in P2, it can emit a greatly enhanced ECL signal compared with its polymer ligand P1 and the Ir(III) model complex using TPrA as a co-reactant in CH3CN solution due to the effective intramolecular metal–ligand charge transfer (MLCT) from the Ir(III)-complex centre to the polymer backbone.
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Analyst
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Analyst publishes analytical and bioanalytical research that reports premier fundamental discoveries and inventions, and the applications of those discoveries, unconfined by traditional discipline barriers.
Recommended Compounds
(3alpha,5beta,6alpha,7alpha)-6-Ethylcholane-3,7,24-triol
CAS Number:
1537866-49-1
Molecular Formula:
C26H46O3
![N-{[(2-Methyl-2-propanyl)oxy]carbonyl}-L-methionylglycine structure](https://static.chemtradehub.com/structs/234/23446-03-9-e1e5.webp "N-{[(2-Methyl-2-propanyl)oxy]carbonyl}-L-methionylglycine structure")
N-{[(2-Methyl-2-propanyl)oxy]carbonyl}-L-methionylglycine
CAS Number:
23446-03-9
Molecular Formula:
C12H22N2O5S
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