A facile approach to ketones via Pd-catalyzed sequential carbonylation of olefins with formic acid

Literature Information

Publication Date 2017-02-22
DOI 10.1039/C7QO00111H
Impact Factor 5.281
Authors

Wenju Chang, Jie Dai, Jingfu Li, Yuan Shi, Wenlong Ren


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Abstract

An effective palladium-catalyzed sequential carbonylation of olefins with formic acid is described. Ketones and the corresponding α,β-enones can be obtained with up to 90% yield. The reaction process is operationally simple and requires no toxic CO.

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Organic Chemistry Frontiers

Organic Chemistry Frontiers
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Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry

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