A facile approach to ketones via Pd-catalyzed sequential carbonylation of olefins with formic acid

Literature Information

Publication Date 2017-02-22
DOI 10.1039/C7QO00111H
Impact Factor 5.281
Authors

Wenju Chang, Jie Dai, Jingfu Li, Yuan Shi, Wenlong Ren


View Original

Abstract

An effective palladium-catalyzed sequential carbonylation of olefins with formic acid is described. Ketones and the corresponding α,β-enones can be obtained with up to 90% yield. The reaction process is operationally simple and requires no toxic CO.

Related Literature

Camptothecin prodrug block copolymer micelles with high drug loading and target specificity

Sue Watson, Anna M. Grabowska

2014-05-15 Paper

DOI: 10.1039/C4PY00369A

Innovative well-defined primary amine-based polyacrylates for plasmid DNA complexation

Hien The Ho, Sagrario Pascual, Véronique Montembault, Nathalie Casse, Laurent Fontaine

2014-06-16 Communication

DOI: 10.1039/C4PY00585F

Diels–Alder cycloaddition and RAFT chain end functionality: an elegant route to fullerene end-capped polymers with control over molecular mass and architecture

Anna Isakova, Christian Burton, Daniel J. Nowakowski, Paul D. Topham

2017-04-11 Paper

DOI: 10.1039/C7PY00394C

Conformation pre-organization in fluorene-based conjugated polymer for simultaneous enhancement of luminescence and charge mobility

Juxin He, Luyang Du, Cong Wang, Mingjian Jiang, Linlin Liu, Yueqi Mo, Zengqi Xie, Bing Yang, Yuguang Ma

2017-01-11 Paper

DOI: 10.1039/C6PY01995A

Front cover

Cover

DOI: 10.1039/C7PY90033C

Peripherally diketopyrrolopyrrole-functionalized dendritic oligothiophenes – synthesis, molecular structure, properties and applications

Qun Luo, Junkai Wang, Yi Lin, Changquan Tang, Junyan Dou, Hongwei Tan, Qingdong Zheng, Chang-Qi Ma, Zheng Cui

2017-01-10 Paper

DOI: 10.1039/C6PY02161A

Differences in electroactive terpolymers based on VDF, TrFE and 2,3,3,3-tetrafluoropropene prepared by batch solution and semi-continuous aqueous suspension polymerizations

Vincent Ladmiral, Thierry Lannuzel, Fabrice Domingues Dos Santos, Bruno Améduri

2016-12-14 Paper

DOI: 10.1039/C6PY01874B

You might also like

Compound Q&A

Are there alternatives to 1-(4-Chlorophenyl)-N-hydroxymethanimine (CAS: 3848-36-0) in synthesis?

When considering alternatives to 1-(4-Chlorophenyl)-N-hydroxymethanimine (CAS: 3...

3848-36-01-(4-Chlorophenyl)-N...
Compound Q&A

How is 3-(4-Bromophenyl)-5-(2-fluorophenyl)-1,2,4-oxadiazole (CAS: 419553-16-5) typically synthesized?

3-(4-Bromophenyl)-5-(2-fluorophenyl)-1,2,4-oxadiazole is synthesized through a m...

419553-16-53-(4-Bromophenyl)-5-...
Compound Q&A

How is 5-Chloro-2-(4-chlorophenyl)-4-methyl-6-[3-(1-piperidinyl)propoxy]pyrimidine (CAS: 1639220-19-1) typically synthesized?

5-Chloro-2-(4-chlorophenyl)-4-methyl-6-[3-(1-piperidinyl)propoxy]pyrimidine (CAS...

1639220-19-15-Chloro-2-(4-chloro...
Compound Q&A

What industries use 2-Chloro-4-(difluoromethoxy)pyridine (CAS: 1206978-15-5)?

2-Chloro-4-(difluoromethoxy)pyridine is used in the pharmaceutical industry for ...

1206978-15-52-Chloro-4-(difluoro...
Compound Q&A

What regulatory guidelines apply to 3-Chloro-6-methylpyridazine (CAS: 1121-79-5)?

3-Chloro-6-methylpyridazine (CAS: 1121-79-5) is classified under the Globally Ha...

1121-79-53-Chloro-6-methylpyr...
Compound Q&A

Are there alternatives to Methyl 4,5-dimethyl-2-nitrobenzoate in synthesis?

Several alternatives can be used in the synthesis of Methyl 4,5-dimethyl-2-nitro...

90922-74-0Methyl 4,5-dimethyl-...
Compound Q&A

Are there alternatives to (2E,2'E)-3,3'-(1,4-Phenylene)bisacrylaldehyde in synthesis?

Alternatives to (2E,2'E)-3,3'-(1,4-Phenylene)bisacrylaldehyde include other acry...

63405-68-5(2E,2'E)-3,3'-(1,4-P...
Compound Q&A

What is 3-Amino-5-chloropyridin-2-ol hydrochloride (CAS: 1261906-29-9)?

3-Amino-5-chloropyridin-2-ol hydrochloride is an organic compound with the CAS n...

1261906-29-93-Amino-5-chloropyri...
Compound Q&A

What precautions should be taken when handling 6,7-Difluoro-2,3-dihydro-4H-chromen-4-one (CAS: 1092349-93-3)?

When handling 6,7-Difluoro-2,3-dihydro-4H-chromen-4-one, it is essential to wear...

1092349-93-36,7-Difluoro-2,3-dih...

Source Journal

Organic Chemistry Frontiers

Organic Chemistry Frontiers
CiteScore: 7.8
Self-citation Rate: 8.7%
Articles per Year: 724

Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry

Recommended Compounds

Recommended Suppliers

Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.