Preparation of a highly reactive polymer click reagent, PEG nitrile N-oxide, and its application in block and star polymer synthesis
Literature Information
Publication Date
2017-02-06
DOI
10.1039/C7PY00100B
Impact Factor
5.582
Authors
Toyokazu Tsutsuba
View Original
Abstract
The polymer nitrile N-oxide containing poly(ethylene glycol) (PEG) skeleton PEG-CNO was synthesized via a stepwise reaction. The catalyst-free click reaction of PEG-CNO with terminal CC bond-tethering compounds afforded the corresponding diblock and multi-arm star polymers in high yields. The click reactions under solvent-free conditions resulted in significant rate acceleration and high yields of the polymers.
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Source Journal
Polymer Chemistry
CiteScore:
8.6
Self-citation Rate:
7.3%
Articles per Year:
457
Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.
Recommended Compounds
![S-[2,3-Bis(palmitoyloxy)propyl]-N-[(9H-fluoren-9-ylmethoxy)(hydroxy)methylene]cysteine structure](https://static.chemtradehub.com/structs/210/210532-98-2-f6a7.webp "S-[2,3-Bis(palmitoyloxy)propyl]-N-[(9H-fluoren-9-ylmethoxy)(hydroxy)methylene]cysteine structure")
S-[2,3-Bis(palmitoyloxy)propyl]-N-[(9H-fluoren-9-ylmethoxy)(hydroxy)methylene]cysteine
CAS Number:
210532-98-2
Molecular Formula:
C53H83NO8S
6-CHLORO-2,3-DIOXO-1,2,3,4-TETRAHYDROQUINOXALINE, 97
CAS Number:
169-14-2
Molecular Formula:
C8H5ClN2O2
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