4-Methyl-2-oxo-2H-chromen-7-yl 2-acetamido-2-deoxy-3-O-(6-deoxy-alpha-L-galactopyranosyl)-beta-D-glucopyranoside
CAS Number:
383160-12-1
Molecular Formula:
C24H31NO12
The effect of metal ions on the viscoelastic properties of thermosensitive sol-to-gel reversible metallo-supramolecular hydrogels
Literature Information
Publication Date
2018-04-04
DOI
10.1039/C7PY02118F
Impact Factor
5.582
Authors
A. Gutierres, S. Pascual, L. Fontaine, S. Piogé, L. Benyahia
View Original
Abstract
Smart metallo-supramolecular hydrogels offer attractive possibilities to combine the properties of hydrogels with the self-assembly features offered by metal–ligand coordination. The preparation of metal-bis(terpyridine-poly(N,N-dimethylacrylamide)-b-poly(N-isopropylacrylamide)) ([M(Tpy-PDMA-b-PNIPAM)2]2+) complexes in aqueous media and their use for the elaboration of hydrogels by thermo-induced micellar aggregation is investigated in this study. The rheological behaviour suggested that the metal-bis complexes based on a copolymer having two distinct hydrophilic blocks self-assemble into flower-like micelles. Moreover, the control of the viscoelastic properties of the hydrogels is notably achieved via an appropriate choice of the nature and the molar equivalent composition of metal ions.
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Source Journal
Polymer Chemistry
CiteScore:
8.6
Self-citation Rate:
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Articles per Year:
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Recommended Compounds
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