A novel aggregate of [Mn2(μ-O)2] units: [Mn8O10(O2CMe)6(H2O)2(bpy)6]4+ with a serpentine core

Literature Information

Publication Date 2003-01-29
DOI 10.1039/B211345G
Impact Factor 6.222
Authors

Anastasios J. Tasiopoulos, Khalil A. Abboud, George Christou


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Abstract

The synthesis, characterization and initial reactivity studies are reported of the mixed-valence (MnIV6MnIII2) title compound, which possesses an unusual serpentine-like core and is the highest average oxidation state (+3.75) Mnx (x > 4) cluster to date.

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