Preparation, structure, and some coordination properties of 2-chloro-3,3-diphenyl-3-thioxo-1-(2,4,6-tri-t-butylphenyl)-1,3-diphosphapropene

Literature Information

Publication Date 2003-01-13
DOI 10.1039/B211230B
Impact Factor 6.222
Authors

Shigekazu Ito, Hongze Liang, Masaaki Yoshifuji


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Abstract

A sterically encumbered 3-thioxo-1,3-diphosphapropene, bearing a PC–PS skeleton, was prepared, characterised, and allowed to react with a carbonyltungsten(0) reagent and iodine affording the corresponding chelate tungsten(0) complex and charge-transfer complex with iodine, respectively, which were analysed by the X-ray crystallography.

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