4-(Bromomethyl)-1-cyclohexyl-2-(trifluoromethyl)benzene
CAS Number:
800381-60-6
Molecular Formula:
C14H16BrF3
High-throughput physicochemical analysis of thermoresponsive polymers
Literature Information
Publication Date
2018-02-07
DOI
10.1039/C7PY02066J
Impact Factor
5.582
Authors
S. J. M. C. Bou, A. R. Connolly, A. V. Ellis
View Original
Abstract
Calculating the lower critical solution temperature (LCST) of a thermoresponsive polymer is an important measure of its physical properties. Here, the LCST of poly(N-isopropylacrylamide) (pNIPAM) was determined by measuring the scattered light intensity in a real-time thermocycler. This method allowed for the investigation of low concentration (μg mL−1) samples in low volumes (μL). Subsequently, the critical micelle temperatures (CMTs) and concentrations (CMCs) were simultaneously recorded in 2 h for over 220 samples of the thermoresponsive copolymers of NIPAM with N-hydroxymethyl acrylamide (HMAM) (pNIPAM-co-HMAM (2.5–12.5 mol% HMAM)). This high-throughput approach paves the way to rapidly ‘map’ the physicochemical properties of low abundance polymers with statistical accuracy.
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Source Journal
Polymer Chemistry
CiteScore:
8.6
Self-citation Rate:
7.3%
Articles per Year:
457
Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.
Recommended Compounds
![Ethyl 4-[8-chloro(5,5,6,6,7-~2~H_5_)-5,6-dihydro-11H-benzo[5,6]cyclohepta[1,2-b]pyridin-11-ylidene]-1-piperidinecarboxylate structure](https://static.chemtradehub.com/structs/102/1020719-57-6-37e2.webp "Ethyl 4-[8-chloro(5,5,6,6,7-~2~H_5_)-5,6-dihydro-11H-benzo[5,6]cyclohepta[1,2-b]pyridin-11-ylidene]-1-piperidinecarboxylate structure")
Ethyl 4-[8-chloro(5,5,6,6,7-~2~H_5_)-5,6-dihydro-11H-benzo[5,6]cyclohepta[1,2-b]pyridin-11-ylidene]-1-piperidinecarboxylate
CAS Number:
1020719-57-6
Molecular Formula:
C22H18D5ClN2O2
![5,10-Dihydroindeno[2,1-a]indene structure](https://static.chemtradehub.com/structs/654/6543-29-9-71ca.webp "5,10-Dihydroindeno[2,1-a]indene structure")
![1-[4-(4-Methyl-1H-imidazol-1-yl)phenyl]ethanone structure](https://static.chemtradehub.com/structs/142/142161-53-3-7f55.webp "1-[4-(4-Methyl-1H-imidazol-1-yl)phenyl]ethanone structure")
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