phosphoryl}methyl 4-methylbenzenesulfonate structure](https://static.chemtradehub.com/structs/864/864068-45-1-ba7c.webp "{[3-(Hexadecyloxy)propoxy](hydroxy)phosphoryl}methyl 4-methylbenzenesulfonate structure")
{[3-(Hexadecyloxy)propoxy](hydroxy)phosphoryl}methyl 4-methylbenzenesulfonate
CAS Number:
864068-45-1
Molecular Formula:
C27H49O7PS
Stereochemical effects on the mechanical and viscoelastic properties of renewable polyurethanes derived from isohexides and hydroxymethylfurfural
Literature Information
Publication Date
2017-07-24
DOI
10.1039/C7PY00949F
Impact Factor
5.582
Authors
Robert J. Kieber, III, Samantha A. Silver, Justin G. Kennemur
View Original
Abstract
Biomass-derived polyurethanes were synthesized using 2,5-bishydroxymethylfuran (BHMF) and diisocyanate functionalized isohexides, isosorbide bis(3-isocyanatopropanoate) (ISBIP) and isomannide bis(3-isocyanatopropanoate) (IMBIP), at varying feed ratios. PU compositions accurately reflect the feed of ISBIP and IMBIP used as determined by NMR spectroscopy and polarimetry measurements. Differential scanning calorimetry, pycnometry, tensile testing, and rheology reveal that the isosorbide versus isomannide content within the PU effects the glass transition temperature, density, and entanglement molar mass ultimately resulting in different mechanical properties at similar molar mass. Other properties, such as thermal stability and amorphous character, remain similar. The isohexide isomer effects on properties are discussed.
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Source Journal
Polymer Chemistry
CiteScore:
8.6
Self-citation Rate:
7.3%
Articles per Year:
457
Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.
Recommended Compounds
cis-3-Amino-1-(trifluoromethyl)cyclobutanol hydrochloride (1:1)
CAS Number:
1408075-16-0
Molecular Formula:
C5H9ClF3NO
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