X-ray absorption near edge structure and first-principles spectral investigations of cationic disorder in MgAl2O4 induced by swift heavy ions

Literature Information

Publication Date 2018-02-01
DOI 10.1039/C7CP07591J
Impact Factor 3.676
Authors

S. Yoshioka, K. Tsuruta, T. Yamamoto, K. Yasuda, S. Matsumura, N. Ishikawa, E. Kobayashi


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Abstract

Cationic disorder in the MgAl2O4 spinel induced by swift heavy ions was investigated using the X-ray absorption near edge structure. With changes in the irradiation fluences of 200 MeV Xe ions, the Mg K-edge and Al K-edge spectra were synchronously changed. The calculated spectra based on density function theory indicate that the change in the experimental spectra was due to cationic disorder between Mg in tetrahedral sites and Al in octahedral sites. These results suggest a high inversion degree to an extent that the completely random configuration is achieved in MgAl2O4 induced by the high density electronic excitation under swift heavy ion irradiation.

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Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
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