Non-percolating small metallic clusters and sharp suppression of metallicity in RE0.55Sr0.45Mn1−xRuxO3 manganites

Literature Information

Publication Date 2018-01-02
DOI 10.1039/C7CP02423A
Impact Factor 3.676
Authors

H. S. Alagoz, I. Živković, K. H. Chow, J. Jung


View Original

Abstract

The origin of the anomalous sharp phase transition from a ferromagnetic metal into a ferromagnetic insulator has been investigated in ruthenium (Ru)-doped RE0.55Sr0.45Mn1−xRuxO3 (0 ≤ x ≤ 0.25) manganites (RESRMO) with RE(A-site) = Sm, Eu and Gd. The transition is independent of RE and occurs at a Ru doping level x of around 0.16–0.18. The analysis of the temperature derivative of the resistivity and the magneto-resistance at high temperatures as a function of x suggests that the suppression of metallicity originates from the doping driven magnetic/spin disorder that coexist within the ferromagnetic metallic/insulating matrix in these compounds.

Related Literature

Poly(9,9′-spirobifluorene-manganese porphyrin): a new catalytic material for oxidation of alkenes by iodobenzene diacetate and iodosylbenzene

Cyril Poriel, Yann Ferrand, Paul le Maux, Joëlle Raul-Berthelot, Gerard Simonneaux

2003-04-02 Communication

DOI: 10.1039/B301717F

Selective formation of siloxane-based hybrid cages with methylene groups in the frameworks

Atsushi Shimojima

2004-10-14 Communication

DOI: 10.1039/B411794H

Efficient immobilisation of Rh-MonoPhos on the aluminosilicate AlTUD-1

Ulf Hanefeld, Isabel W. C. E. Arends, Adriaan J. Minnaard, Thomas Maschmeyer, Roger A. Sheldon

2004-10-26 Communication

DOI: 10.1039/B411506F

A new route to fullerene substituted phenylalanine derivatives

Jianzhong Yang, Andrew R. Barron

2004-10-25 Communication

DOI: 10.1039/B411118D

Supramolecular control of complexation-induced fluorescence change of water-soluble, β-cyclodextrin-modified CdS quantum dots

Kumaranand Palaniappan, Stephen A. Hackney, Jian Liu

2004-10-11 Communication

DOI: 10.1039/B409075F

Palladium catalysed cyclisation–carbonylation of enynes to give cyclic γ,δ-unsaturated acids

Varinder K. Aggarwal, Mike Butters, Paul W. Davies

2003-04-02 Communication

DOI: 10.1039/B300719G

Iron(iii) salen-type catalysts for the cross-coupling of aryl Grignards with alkyl halides bearing β-hydrogens

Robin B. Bedford, Duncan W. Bruce, Robert M. Frost, John W. Goodby, Michael Hird

2004-10-27 Communication

DOI: 10.1039/B413790F

Highly efficient bromination of aromatic compounds using 3-methylimidazolium tribromide as reagent/solvent

Cinzia Chiappe, Elsa Leandri, Daniela Pieraccini

2004-09-30 Communication

DOI: 10.1039/B410796A

Cyclopropyl fatty acids implicate a radical but not a cation as an intermediate in P450BM3-catalysed hydroxylations

Max J. Cryle, Julia M. U. Stuthe, Paul R. Ortiz de Montellano, James J. De Voss

2004-01-27 Communication

DOI: 10.1039/B315911F

Modified micro-space using self-organized nanoparticles for reduction of methylene blue

Xianying Li, Hongzhi Wang, Kouzou Inoue, Masato Uehara, Hiroyuki Nakamura, Masaya Miyazaki, Eiichi Abe, Hideaki Maeda

2003-03-18 Communication

DOI: 10.1039/B300765K

You might also like

Compound Q&A

What industries use (1R,3S)-1,3-Cyclopentanediol (CAS: 16326-97-9)?

(1R,3S)-1,3-Cyclopentanediol finds applications in various industries. In the ph...

16326-97-9(1R,3S)-1,3-Cyclopen...
Compound Q&A

What precautions should be taken when handling N'-[4-(Dimethylamino)phenyl]-N,N-dimethyl-1,4-benzenediamine (CAS: 637-31-0)?

When handling N'-[4-(Dimethylamino)phenyl]-N,N-dimethyl-1,4-benzenediamine, it i...

637-31-0N'-[4-(Dimethylamino...
Compound Q&A

Are there alternatives to 5-(2,4-Difluorophenyl)-2-methoxypyrimidine (CAS: 1352318-16-1) in synthesis?

There are several alternatives to 5-(2,4-Difluorophenyl)-2-methoxypyrimidine in ...

1352318-16-15-(2,4-Difluoropheny...
Compound Q&A

What regulatory guidelines apply to 1-(3-Methoxyphenoxy)propan-2-ol (CAS: 382141-68-6)?

1-(3-Methoxyphenoxy)propan-2-ol (CAS: 382141-68-6) must comply with the Globally...

382141-68-61-(3-Methoxyphenoxy)...
Compound Q&A

Is Tetrodotoxin Citrate (CAS: 18660-81-6) safe?

Tetrodotoxin Citrate is extremely dangerous and should be handled with extreme c...

18660-81-6Tetrodotoxin Citrate
Compound Q&A

What are the main uses of 2-Methyl-2-propanyl [(1R,3S)-3-hydroxycyclopentyl]carbamate (CAS: 225641-84-9)?

2-Methyl-2-propanyl [(1R,3S)-3-hydroxycyclopentyl]carbamate (CAS: 225641-84-9) i...

225641-84-92-Methyl-2-propanyl ...
Compound Q&A

How should waste containing 4-(2-Hydroxyhexafluoroisopropyl)Benzoic Acid (CAS: 16261-80-6) be handled?

Waste containing 4-(2-Hydroxyhexafluoroisopropyl)Benzoic Acid (CAS: 16261-80-6) ...

16261-80-64-(2-Hydroxyhexafluo...
Compound Q&A

How is 2-Methyl-2-proanyl {(2S)-1-[(benzyloxy)amino]-3-hydroxy-3-methyl-1-oxo-2-butanyl}carbamate (CAS: 102507-19-7) typically synthesized?

2-Methyl-2-proanyl {(2S)-1-[(benzyloxy)amino]-3-hydroxy-3-methyl-1-oxo-2-butanyl...

102507-19-72-Methyl-2-propanyl ...
Compound Q&A

What is Benzeneethanamine, α-ethyl-, hydrochloride (1:1) (CAS: 20735-15-3)?

Benzeneethanamine, α-ethyl-, hydrochloride (1:1) is an organic compound with the...

20735-15-3Benzeneethanamine, α...
Compound Q&A

Are there alternatives to 3-{(E)-[4-(Dimethylamino)phenyl]diazenyl}benzoic acid (CAS: 20691-84-3) in synthesis?

In the synthesis of compounds similar to 3-{(E)-[4-(Dimethylamino)phenyl]diazeny...

20691-84-33-{(E)-[4-(Dimethyla...

Source Journal

Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
CiteScore: 5.5
Self-citation Rate: 10.3%
Articles per Year: 3036

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

Recommended Compounds

Recommended Suppliers

Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.