Poly(9,9′-spirobifluorene-manganese porphyrin): a new catalytic material for oxidation of alkenes by iodobenzene diacetate and iodosylbenzene

Literature Information

Publication Date 2003-04-02
DOI 10.1039/B301717F
Impact Factor 6.222
Authors

Cyril Poriel, Yann Ferrand, Paul le Maux, Joëlle Raul-Berthelot, Gerard Simonneaux


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Abstract

Anodic oxidation of tetraspirobifluorene-manganese porphyrin lead to the coating of the working electrode by insoluble electroactive poly(9,9′-spirobifluorene-manganese porphyrin) films for which electrochemical behaviour and physicochemical properties are described; these polymeric materials are able to catalyze the heterogeneous epoxidation of styrene with iodobenzene diacetate and iodosylbenzene.

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