Hyperbranched supramolecular polymer constructed from twisted cucurbit[14]uril and porphyrin via host–guest interactions

Literature Information

Publication Date 2016-07-21
DOI 10.1039/C6QO00310A
Impact Factor 5.281
Authors

Zhongzheng Gao, Jing Zhang, Nana Sun, Ying Huang, Zhu Tao, Xin Xiao, Jianzhuang Jiang


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Abstract

A novel supramolecular polymer Q[14]-TBPyP was successfully constructed from a host twisted cucurbit[14] (Q[14]) molecule and a four-arm 5,10,15,20-tetrakis(N-butyl-4-pyridinium)porphyrin tetrabromide (TBPyP) guest molecule depending on the host–guest interactions and characterized by NMR, ITC, DLS, electronic absorption, and fluorescence spectroscopy, representing the first cucurbit[14]uril-involved host–guest supramolecular polymer.

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Organic Chemistry Frontiers

Organic Chemistry Frontiers
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Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry

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