Azide groups in high oxidation state Mn carboxylate chemistry: a new Mn11 complex and its conversion to a Mn25azide complex with Me3SiN3

Literature Information

Publication Date 2009-04-22
DOI 10.1039/B902016K
Impact Factor 6.222
Authors

Theocharis C. Stamatatos, Alina Vinslava, Khalil A. Abboud, George Christou


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Abstract

A new high oxidation state MnIII/IV11carboxylate complex has been prepared and then converted to a MnII/III25 azide/carboxylate cluster with Me3SiN3; the Mn25 product is the initial example of a higher oxidation state Mn azide complex not stabilized by any chelate ligands.

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