Reaction of alkenecarboxylic acids with isocyanates via rhodium(iii)-catalyzed C–H activation: a versatile route to cyclic imides
Literature Information
Publication Date
2016-06-13
DOI
10.1039/C6QO00119J
Impact Factor
5.281
Authors
Yun Liu, Hai ning Wang, Wen bo Liu, Chao-Jun Li
View Original
Abstract
Under rhodium(III) catalysis, substituted propenoic acids successfully reacted with aryl isocyanates to provide cyclic imides via direct functionalization of the β-alkenyl C–H bond followed by intramolecular cyclization. The cascade process has been corroborated by the isolated intermediate. The reaction provides direct access to cyclic imides from readily available starting materials.
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Source Journal
Organic Chemistry Frontiers
CiteScore:
7.8
Self-citation Rate:
8.7%
Articles per Year:
724
Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry
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[5-fluoro-2-(morpholine-4-carbonyl)phenyl]boronic acid
CAS Number:
1217501-26-2
Molecular Formula:
C11H13BFNO4
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2-Methyl-2-propanyl {3-[4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]-3-oxetanyl}carbamate
CAS Number:
1279090-25-3
Molecular Formula:
C20H30BNO5
N1,N1-Bis(4-aminophenyl)benzene-1,4-diamine trihydrochloride
CAS Number:
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Molecular Formula:
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