Ascorbic acid promoted [4 + 2] benzannulation: a mild, operationally simple approach to the synthesis of phenanthrenes
Literature Information
Publication Date
2016-03-21
DOI
10.1039/C6QO00020G
Impact Factor
5.281
Authors
Mei-jie Bu, Guo-ping Lu, Chun Cai
View Original
Abstract
A mild, simple and metal-free radical [4 + 2] benzannulation for the generation of phenanthrenes has been developed. A substoichiometric reductant, ascorbic acid (vitamin C), is harnessed as the radical initiator. This method has a broad substrate scope, and various substituted phenanthrenes were obtained in moderate to good yields at room temperature without irradiation.
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Source Journal
Organic Chemistry Frontiers
CiteScore:
7.8
Self-citation Rate:
8.7%
Articles per Year:
724
Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry
Recommended Compounds
![2-{3-[4-(3-Chlorophenyl)-1-piperazinyl]propyl}[1,2,4]triazolo[4,3-a]pyridin-3(2H)-one hydrochloride (1:1) structure](https://static.chemtradehub.com/structs/253/25332-39-2-496e.webp "2-{3-[4-(3-Chlorophenyl)-1-piperazinyl]propyl}[1,2,4]triazolo[4,3-a]pyridin-3(2H)-one hydrochloride (1:1) structure")
2-{3-[4-(3-Chlorophenyl)-1-piperazinyl]propyl}[1,2,4]triazolo[4,3-a]pyridin-3(2H)-one hydrochloride (1:1)
CAS Number:
25332-39-2
Molecular Formula:
C19H23Cl2N5O
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