![6,6-Dimethylbicyclo[3.1.1]hept-2-ene-2-carbaldehyde structure](https://static.chemtradehub.com/structs/564/564-94-3-e746.webp "6,6-Dimethylbicyclo[3.1.1]hept-2-ene-2-carbaldehyde structure")
A Cu(ii) metal–organic framework as a recyclable catalyst for ARGET ATRP
Literature Information
Publication Date
2016-11-08
DOI
10.1039/C6PY01844K
Impact Factor
5.582
Authors
Hui-Chun Lee, Markus Antonietti, Bernhard V. K. J. Schmidt
View Original
Abstract
A Cu(II) MOF can serve as an efficient catalyst for activators regenerated by electron transfer atom transfer radical polymerization (ARGET ATRP), e.g. for the synthesis of poly(benzyl methacrylate) (PBzMA) and polystyrene (PS). Furthermore, poly(isoprene) (PI) and poly(4-vinylpyridine) (P4VP) can be formed in a controlled fashion as well, which used to be challenging to achieve by traditional strategies. Taking advantage of the heterogeneous nature of the catalyst, recycling via centrifugation and repeated utilization for at least six cycles are demonstrated.
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Source Journal
Polymer Chemistry
CiteScore:
8.6
Self-citation Rate:
7.3%
Articles per Year:
457
Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.
Recommended Compounds
4-Methyl-2-oxo-2H-chromen-7-yl 2-acetamido-2-deoxy-3-O-(6-deoxy-alpha-L-galactopyranosyl)-beta-D-glucopyranoside
CAS Number:
383160-12-1
Molecular Formula:
C24H31NO12
![6-(Benzyloxy)-8-(2-bromoacetyl)-2H-benzo[b][1,4]oxazin-3(4H)-one structure](https://static.chemtradehub.com/structs/926/926319-53-1-2287.webp "6-(Benzyloxy)-8-(2-bromoacetyl)-2H-benzo[b][1,4]oxazin-3(4H)-one structure")
6-(Benzyloxy)-8-(2-bromoacetyl)-2H-benzo[b][1,4]oxazin-3(4H)-one
CAS Number:
926319-53-1
Molecular Formula:
C17H14BrNO4
![[(2R)-6,6-Dimethyl-2-morpholinyl]methanol hydrochloride (1:1) structure](https://static.chemtradehub.com/structs/141/1416444-88-6-e06a.webp "[(2R)-6,6-Dimethyl-2-morpholinyl]methanol hydrochloride (1:1) structure")
[(2R)-6,6-Dimethyl-2-morpholinyl]methanol hydrochloride (1:1)
CAS Number:
1416444-88-6
Molecular Formula:
C7H16ClNO2
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