![6-Bromo-2,3-dihydro-1H-pyrido[2,3-b][1,4]oxazine structure](https://static.chemtradehub.com/structs/120/1203499-17-5-b4d1.webp "6-Bromo-2,3-dihydro-1H-pyrido[2,3-b][1,4]oxazine structure")
6-Bromo-2,3-dihydro-1H-pyrido[2,3-b][1,4]oxazine
CAS Number:
1203499-17-5
Molecular Formula:
C7H7BrN2O
Block copolymers based on 2-methyl- and 2-phenyl-oxazoline by metallocene-mediated cationic ring-opening polymerization: synthesis and characterization
Literature Information
Publication Date
2016-03-28
DOI
10.1039/C6PY00405A
Impact Factor
5.582
Authors
Maria-Evgenia Kourti, Eirini Fega, Marinos Pitsikalis
View Original
Abstract
Previous studies have shown that the cationic polymerization of oxazolines, lactones and vinyl ethers can be efficiently promoted by metallocene complexes activated by floroaryl borates. Taking this into account, different series of block copolymers, i.e. PPhOx-b-PMeOx, Pε-CL-b-PMeOx, Pε-CL-b-PPhOx, PEVE-b-PPhOx, along with the triblock terpolymers, Pε-CL-b-PMeOx-b-PEVE and Pε-CL-b-PPhOx-b-PEVE, were prepared by sequential addition of monomers. The synthesis was monitored by SEC and NMR spectroscopy, showing that well-defined products are obtained in most cases. The microphase separation of the samples was studied by DSC and their thermal stability by TGA measurements.
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Source Journal
Polymer Chemistry
CiteScore:
8.6
Self-citation Rate:
7.3%
Articles per Year:
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