Cation/macromolecule interaction in alkaline cellulose solution characterized with pulsed field-gradient spin-echo NMR spectroscopy

Literature Information

Publication Date 2017-02-20
DOI 10.1039/C6CP08744B
Impact Factor 3.676
Authors

Sen Wang, Peng Sun, Rongrong Zhang, Ang Lu, Maili Liu, Lina Zhang


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Abstract

As a breakthrough to the traditional 1H diffusometry, the interaction of cations with cellulose is investigated via7Li and 23Na PFG-SE NMR. The diffusion coefficient of Li+ decreases more than that of Na+ with the addition of cellulose, which indicates a stronger binding of LiOH with the macromolecule. Therefore, a new, facile, accurate and repeatable method to characterize ion/polymer interactions is established.

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Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
CiteScore: 5.5
Self-citation Rate: 10.3%
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Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

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