Initial dissolution of D2O at the gas–liquid interface of the ionic liquid [C4min][NTf2] associated with hydrogen-bond network formation
Literature Information
H. Ohoyama, T. Teramoto
We have studied the initial dissolution of D2O at the interfacial surface of the flowing jet sheet beam of the ionic liquid (IL) [C4min][NTf2] using the King and Wells method as a function of both the temperature and collision energy of the IL. The initial dissolution probability of D2O into the IL [C4min][NTf2] was found to follow the general propensity that the solubility of gases into a liquid decreases with temperature. However, a large partial molar enthalpy and entropy for the initial dissolution of D2O in the IL [C4min][NTf2] were observed from the temperature dependence of the initial dissolution probability: ΔHl = −53 ± 8 kJ mol−1, ΔSl = −210 ± 30 J mol−1 K−1. In addition, it was found that the collision energy significantly reduced the initial dissolution probability. We propose that the associated D2O molecules at the interface of the IL [C4min][NTf2] make a hydrogen-bond network around the [NTf2]− anion before dissolution into the deeper portion of the interface layer.
Recommended Journals

New Journal of Chemistry

Saudi Pharmaceutical Journal

Nature Medicine

Russian Journal of General Chemistry

Journal of Peptide Science

Crystallography Reports

Current Opinion in Colloid & Interface Science

Chemistry Education Research and Practice

Russian Chemical Bulletin

Organic Process Research & Development
Related Literature
Fluorescent carbon nanomaterials: “quantum dots” or nanoclusters?
Mariia O. Dekaliuk, Oleg Viagin, Yuriy V. Malyukin, Alexander P. Demchenko
DOI: 10.1039/C4CP00138A
1064 nm SERS of NIR active hollow gold nanotags
H. Kearns, N. C. Shand, W. E. Smith, K. Faulds, D. Graham
DOI: 10.1039/C4CP04281F
CdS nanorod arrays with TiO2 nano-coating for improved photostability and photocatalytic activity
Liangpeng Wu, Yulan Zhang, Xinjun Li, Chaoping Cen
DOI: 10.1039/C4CP01347F
Spin effects in thermoelectric phenomena in SiC nanoribbons
K. Zberecki, R. Swirkowicz, M. Wierzbicki
DOI: 10.1039/C4CP04884A
Determination of protein binding affinities within hydrogel-based molecularly imprinted polymers (HydroMIPs)
Hazim F. EL-Sharif, Daniel M. Hawkins, Derek Stevenson, Subrayal M. Reddy
DOI: 10.1039/C4CP01798F
Michaelis–Menten kinetics under non-isothermal conditions
Anders Lervik, Hong Qian
DOI: 10.1039/C4CP04334K
Is the contribution of cis and trans protonated 5-methylcytosine-SO3− isomers equal in the conversion to thymine-SO3− under bisulfite conditions? A theoretical perspective
Lu Wang, Caiying Zhang, Wenliang Wang, Suotian Min, Daodao Hu
DOI: 10.1039/C4CP00387J
Experimental and theoretical study of enol–keto prototropic tautomerism and photophysics of azomethine–BODIPY dyads
Zhong-Hua Pan, Jing-Wei Zhou, Geng-Geng Luo
DOI: 10.1039/C4CP02151G
Steric self-assembly of laterally confined organic semiconductor molecule analogues
Björn Arnold, Matt Bumstead, Ayse Turak
DOI: 10.1039/C4CP02331E
Structural and silver/vanadium ratio effects on silver vanadium phosphorous oxide solution formation kinetics: Impact on battery electrochemistry
David C. Bock
DOI: 10.1039/C4CP04819A
You might also like
Is 2-(2-chloroacetamido)-3-phenylpropanoic acid (CAS: 7765-11-9) safe?
2-(2-Chloroacetamido)-3-phenylpropanoic acid (CAS: 7765-11-9) is generally consi...
Is 2-(Benzyloxy)-5-bromobenzoic acid (CAS: 62176-31-2) safe?
2-(Benzyloxy)-5-bromobenzoic acid can be handled safely if appropriate precautio...
What is (4-Methyl-1,2,5-oxadiazol-3-yl)methanamine hydrochloride (CAS: 1159825-48-5)?
(4-Methyl-1,2,5-oxadiazol-3-yl)methanamine hydrochloride is a chemical compound ...
What is 2-(5-Hexylthiophen-2-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane (CAS: 917985-54-7)?
2-(5-Hexylthiophen-2-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane (CAS: 917985-54...
Are there alternatives to 4-(8-Methyl-9H-1,3-dioxolo[4,5-h][2,3]benzodiazepin-5-yl)benzenamine (CAS: 102771-26-6) in synthesis?
While 4-(8-Methyl-9H-1,3-dioxolo[4,5-h][2,3]benzodiazepin-5-yl)benzenamine (CAS:...
What is the market or research trend for tert-butyl 3-hydroxy-4,5,7,8-tetrahydro-2H-pyrazolo[3,4-d]azepine-6-carboxylate (CAS: 851376-80-2)?
The market for tert-butyl 3-hydroxy-4,5,7,8-tetrahydro-2H-pyrazolo[3,4-d]azepine...
How should waste containing 3,5-Diamino-1H-pyrazole-4-carbonitrile (CAS: 6844-58-2) be handled?
Waste containing 3,5-Diamino-1H-pyrazole-4-carbonitrile (CAS: 6844-58-2) should ...
How is (6-Fluoro-3-pyridinyl)boronic acid (CAS: 351019-18-6) typically synthesized?
(6-Fluoro-3-pyridinyl)boronic acid can be synthesized through the reaction of 6-...
What industries use Dibenzyl carbonimidoylbiscarbamate (CAS: 10065-79-9)?
Dibenzyl carbonimidoylbiscarbamate (CAS: 10065-79-9) finds applications in vario...
What is the market or research trend for (beta,beta,2,3,4,5,6-~2~H_7_)Phenylalanine (CAS: 74228-83-4)?
The market for (beta,beta,2,3,4,5,6-~2~H_7_)Phenylalanine (CAS: 74228-83-4) is g...
Source Journal
Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

![3-[4-(difluoromethoxy)phenyl]-2-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)propanoic acid structure 3-[4-(difluoromethoxy)phenyl]-2-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)propanoic acid structure](https://static.chemtradehub.com/structs/149/1496564-27-2-952e.webp)
![(1S)-1,5-Anhydro-2-O-alpha-L-arabinopyranosyl-1-[5-hydroxy-7-({6-O-[3-(4-hydroxy-3-methoxyphenyl)propanoyl]-beta-D-glucopyranosyl}oxy)-2-(4-hydroxyphenyl)-4-oxo-4H-chromen-6-yl]-D-glucitol structure (1S)-1,5-Anhydro-2-O-alpha-L-arabinopyranosyl-1-[5-hydroxy-7-({6-O-[3-(4-hydroxy-3-methoxyphenyl)propanoyl]-beta-D-glucopyranosyl}oxy)-2-(4-hydroxyphenyl)-4-oxo-4H-chromen-6-yl]-D-glucitol structure](https://static.chemtradehub.com/structs/225/2252345-81-4-bcff.webp)

