Non-covalent interaction of benzene with methanol and diethyl ether solid surfaces

Literature Information

Publication Date 2016-07-07
DOI 10.1039/C6CP01787H
Impact Factor 3.676
Authors

Demian Marchione, Martin R. S. McCoustra


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Abstract

We present laboratory experiments on binary, layered ices comprised of benzene (C6H6) on methanol (CH3OH) and on diethyl ether (CH3CH2OCH2CH3). Temperature programmed desorption (TPD) and reflection–absorption infrared spectroscopy (RAIRS) have been used to investigate the growth mechanisms in these systems. Ab initio quantum chemical calculations on simple gas-phase model clusters are used to aid interpretation of the experimental data by highlighting the key interactions established at the interface. Our observations are consistent with C6H6 forming islands on CH3OH, although evidence of strong hydrogen bonding interactions indicates some degree of surface wetting. In contrast, layer-by-layer growth is proposed for C6H6 on the CH3CH2OCH2CH3 substrate.

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Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
CiteScore: 5.5
Self-citation Rate: 10.3%
Articles per Year: 3036

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

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