Functionalized dicyandiamide–formaldehyde polymers as efficient heterogeneous catalysts for conversion of CO2 into organic carbonates

Literature Information

Publication Date 2014-02-28
DOI 10.1039/C3GC42331J
Impact Factor 10.182
Authors

Jian Sun, Wei-Guo Cheng, Jin-Quan Wang, Hong-Yan He, Suo-Jiang Zhang


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Abstract

The application of the dicyandiamide–formaldehyde polymer (DFP), which is a kind of organic polymer flocculant, as a supporter for conversion of CO2 into organic carbonates was studied in this work, and four kinds of dicyandiamide–formaldehyde polymers were synthesized and employed as efficient single component, metal-free, multifunctional, polyquaternium catalysts for cycloaddition of CO2 with epoxides. The results indicated that the ammonium bromide modified dicyandiamide–formaldehyde polymer (ABMDFP) was the optimal catalyst among the four polymers and was observed to be suitable for various substrates. A possible mechanism of ring-opening of epoxides assisted by the hydroxyl and activation of CO2 induced by amines was proposed. In addition, the catalyst could be easily recovered and reused six times with only a slight loss of catalytic activity. Furthermore, the catalyst exhibited good activity in the synthesis of dimethyl carbonate (DMC) through a transesterification reaction. The functional organic polymers in this study were proved to be efficient heterogeneous catalysts for the cycloaddition reaction of CO2, which was applicable to the development of fixed-bed continuous flow reactors.

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