Spectroscopic observation of nitrogen anions N− in solid matrices

Literature Information

Publication Date 2016-05-18
DOI 10.1039/C6CP01080F
Impact Factor 3.676
Authors

I. B. Bykhalo, A. A. Pelmenev, S. Mao, A. Meraki, P. T. McColgan, D. M. Lee, V. V. Khmelenko


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Abstract

Analysis of old and recent experiments on thermoluminescence of cryocrystals and nanoclusters of N2, Ne, Ar, and Kr containing stabilized nitrogen atoms, suggests that the so-called γ-line may correspond to the bound–bound transition 1D–3P of nitrogen anions N− formed in solids by the association of delocalized electrons and metastable nitrogen atoms N(2D). The recent observations of the γ-line were accompanied by simultaneous luminescence of metastable nitrogen N(2D) atoms and exoelectron emission. The fine structure of the γ-line at 793 nm has been experimentally observed and investigated for the first time.

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Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
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