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Gold(i) catalyzed [1,3] O → C rearrangement of benzylvinyl ethers
Literature Information
Publication Date
2016-01-26
DOI
10.1039/C5QO00397K
Impact Factor
5.281
Authors
Chandrababu Naidu Kona, Mahesh N. Patil, Chepuri V. Ramana
View Original
Abstract
A simple procedure for the preparation of 3-(hetero)arylpropionaldehydes has been developed employing a gold-catalyzed [1,3]-rearrangement of vinyl ethers. Using this protocol, Canthoxal, an aromatic aldehyde used in perfumery, has been prepared on a gram scale.
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Source Journal
Organic Chemistry Frontiers
CiteScore:
7.8
Self-citation Rate:
8.7%
Articles per Year:
724
Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry
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