Cyclometallated ruthenium(ii) complexes with ditopic thienyl–NHC ligands: syntheses and alkyne annulations‡
Literature Information
Publication Date
2015-10-12
DOI
10.1039/C5QO00292C
Impact Factor
5.281
Authors
Xiaoke Xie, Han Vinh Huynh
View Original
Abstract
A series of six [RuX(2-thienyl–NHC)(p-cymene)] complexes (9a–c and 10–14; X = halido) have been prepared via NHC directed C–H activation. All complexes have been fully characterized, and the molecular structures of four complexes are reported. The rotational barrier of the N-benzyl substituent in the bromido complex 9b has been measured by variable temperature 1H NMR spectroscopy. Preliminary reactivity studies of complex 12 with alkynes provided four new annulated aza-heterocyclic thiophenes.
Recommended Journals
Journal of Asian Natural Products Research
Main Group Chemistry
Heteroatom Chemistry
Chinese Journal of Chemistry
Herald of the Russian Academy of Sciences
Topics in Catalysis
Journal of the Indian Institute of Science
Bioorganic & Medicinal Chemistry Letters
Acta Metallurgica Sinica-English Letters
Biocatalysis and Biotransformation
Related Literature
Photoredox Suzuki coupling using alkyl boronic acids and esters
Kanak Kanti Das, Somenath Mahato, Debraj Ghorai, Sutapa Dey, Santanu Panda
2023-12-14
Research Article
DOI: 10.1039/D3QO01838E
One-pot ipso-hydroxylation and ortho-/para-halogenation of (hetero)arylboronic acids under tungsten catalysis
Jiao Kang
2023-12-11
Research Article
DOI: 10.1039/D3QO01455J
Electrochemical difunctionalization of alkenes and alkynes for the synthesis of organochalcogens involving C–S/Se bond formation
Jianchao Liu, Jie-Ping Wan, Yunyun Liu
2023-11-23
Review Article
DOI: 10.1039/D3QO01844J
Solvent- and catalyst-dependent palladium-catalyzed switchable chemodivergent cascade cyclizations of trimethylenemethanes with ortho-formyl cinnamates
Shuyuan Liang, Liangjian Tang, Ying Chen, Xueqiu Huang, Xueqin Wei
2023-11-30
Research Article
DOI: 10.1039/D3QO01525D
Atroposelective synthesis of N–N axially chiral pyrrolyl(aza)-quinolinone by de novo ring formation
Qiwen Huang, Yanze Li, Cun Yang, Wendan Wu, Jingjie Hai, Xinyao Li
2023-12-04
Research Article
DOI: 10.1039/D3QO01877F
Practical synthesis and divergent optimization of halichonine B for the discovery of novel pharmaceutical leads
Shengxin Sun, Juan Yang, Shengkun Li
2023-12-04
Research Article
DOI: 10.1039/D3QO01816D
Photocatalytic formation of P–S bonds via CdSeS/CdZnS quantum dots under visible light irradiation
Zi-Jun Lei, Yue-Yue Zhang, Hui-Ling Lu, Fu-Gang Zhao, Jian-Hai Zhou, Xiaogang Peng
2023-11-23
Research Article
DOI: 10.1039/D3QO01560B
An umpolung strategy for chemoselective metal-free [4 + 2] annulation of azlactones: access to tetrahydro-β-carbolin 1,3-diketone frameworks
Meng Wang, Ze-Hong Zheng, Mu-Qiu Chen, Gu Zhan, Jie Wang, Qian-Qian Yang, Wei Huang
2023-12-12
Research Article
DOI: 10.1039/D3QO01184D
Water-soluble hexakis-imidazolium cages: synthesis and selective binding of sodium urate
Sheng-Yi Zhuang, Gang Wu, Jian-Da Sun, Jiangshan Zhang, Jiabin Xing, Yan Wu, Hui Wang, Zhan-Ting Li, Dan-Wei Zhang
2023-11-27
Research Article
DOI: 10.1039/D3QO01780J
You might also like
Compound Q&A
How should 2-Methylbenzene-1,4-diamine dihydrochloride (CAS: 615-45-2) be stored?
2-Methylbenzene-1,4-diamine dihydrochloride (CAS: 615-45-2) should be stored in ...
615-45-22-Methylbenzene-1,4-...
Compound Q&A
Is (1S,4S)-2,5-Diazabicyclo[2.2.1]heptane dihydrobromide (CAS: 132747-20-7) safe?
(1S,4S)-2,5-Diazabicyclo[2.2.1]heptane dihydrobromide is generally considered sa...
132747-20-7(1S,4S)-2,5-Diazabic...
Compound Q&A
What industries use (6-Chloropyridazin-3-YL)methanamine (CAS: 871826-15-2)?
(6-Chloropyridazin-3-YL)methanamine finds applications in the pharmaceutical ind...
871826-15-2(6-Chloropyridazin-3...
Compound Q&A
What are the main uses of 2-Fluoro-3-methylphenol (CAS: 77772-72-6)?
2-Fluoro-3-methylphenol is primarily used in the synthesis of pharmaceuticals, p...
77772-72-62-Fluoro-3-methylphe...
Compound Q&A
What precautions should be taken when handling 3-Methoxy-4-nitrobenzonitrile (CAS: 177476-75-4)?
When handling 3-Methoxy-4-nitrobenzonitrile, it is important to wear appropriate...
177476-75-43-Methoxy-4-nitroben...
Compound Q&A
What precautions should be taken when handling 1,3-Oxazolo[4,5-b]pyridine-2(3H)-thione (CAS: 211949-57-4)?
When handling 1,3-Oxazolo[4,5-b]pyridine-2(3H)-thione (CAS: 211949-57-4), it is ...
211949-57-4[1,3]Oxazolo[4,5-b]p...
Compound Q&A
What regulatory guidelines apply to 4-Ethynylbenzamide (CAS: 90347-86-7)?
4-Ethynylbenzamide (CAS: 90347-86-7) falls under various regulatory guidelines i...
90347-86-74-Ethynylbenzamide
Compound Q&A
What are the main uses of 3-(2-Ethylphenyl)-2-thioxo-4-imidazolidinone (CAS: 186822-57-1)?
3-(2-Ethylphenyl)-2-thioxo-4-imidazolidinone is primarily used as an intermediat...
186822-57-13-(2-Ethylphenyl)-2-...
Compound Q&A
What is (2-Fluoro-6-methoxyphenyl)acetic acid (CAS: 500912-19-6)?
(2-Fluoro-6-methoxyphenyl)acetic acid, also known as 4-fluoro-3-methoxybenzoic a...
500912-19-6(2-Fluoro-6-methoxyp...
Compound Q&A
What is the market or research trend for 2-[4-(Hydroxymethyl)phenoxy]ethanol (CAS: 102196-18-9)?
Market trends for 2-[4-(Hydroxymethyl)phenoxy]ethanol (CAS: 102196-18-9) indicat...
102196-18-92-[4-(Hydroxymethyl)...
Source Journal
Organic Chemistry Frontiers
CiteScore:
7.8
Self-citation Rate:
8.7%
Articles per Year:
724
Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry
Recommended Compounds
(S)-(9H-Fluoren-9-yl)methyl (pyrrolidin-2-ylmethyl)carbamate hydrochloride
CAS Number:
1217813-15-4
Molecular Formula:
C20H23ClN2O2
![[(5-Methyl-1,3,4-thiadiazol-2-yl)sulfanyl]acetic acid structure](https://static.chemtradehub.com/structs/509/50918-26-8-4ce8.webp "[(5-Methyl-1,3,4-thiadiazol-2-yl)sulfanyl]acetic acid structure")
[(5-Methyl-1,3,4-thiadiazol-2-yl)sulfanyl]acetic acid
CAS Number:
50918-26-8
Molecular Formula:
C5H6N2O2S2
![4-[(2-{2-[2-(2-Aminoethoxy)ethoxy]ethoxy}ethyl)amino]-2-(2,6-dioxo-3-piperidinyl)-1H-isoindole-1,3(2H)-dione structure](https://static.chemtradehub.com/structs/209/2093416-31-8-3162.webp "4-[(2-{2-[2-(2-Aminoethoxy)ethoxy]ethoxy}ethyl)amino]-2-(2,6-dioxo-3-piperidinyl)-1H-isoindole-1,3(2H)-dione structure")
4-[(2-{2-[2-(2-Aminoethoxy)ethoxy]ethoxy}ethyl)amino]-2-(2,6-dioxo-3-piperidinyl)-1H-isoindole-1,3(2H)-dione
CAS Number:
2093416-31-8
Molecular Formula:
C21H28N4O7
Recommended Suppliers
Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.