Direct borylation of benzyl alcohol and its analogues in the absence of bases
Literature Information
Zhi-Chao Cao, Fei-Xian Luo, Wen-Juan Shi
Direct borylation of arylmethanols to synthesize important and useful benzylboronates was carried out through Pd(OAc)2-catalyzed sp3 C–O activation. This borylation is compatible with various functional groups under mild conditions in the absence of any bases, offering an atom- and step-economical way to produce benzylboron compounds.
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