N1,N1-Bis(4-aminophenyl)benzene-1,4-diamine trihydrochloride
CAS Number:
114254-48-7
Molecular Formula:
C18H21Cl3N4
Photoredox catalyzed release of carbon-based radicals from 2-substituted-1,3-imidazolidines
Literature Information
Publication Date
2023-12-07
DOI
10.1039/D3QO01856C
Impact Factor
5.281
Authors
Adrián Luguera Ruiz, Elena Mariani, Stefano Protti, Maurizio Fagnoni
View Original
Abstract
In the frame of developing easily oxidizable compounds for the photorelease of carbon-based radicals, we describe herein the use of 2-substituted-1,3-imidazolidines. These compounds (Eoxca. 1 V vs. SCE) were used to generate (substituted) alkyl radicals under photoredox conditions. The radicals smoothly added to electron-poor CC bonds for the forging of C(sp3)–C(sp3) bonds under metal-free conditions. Acridinium salts and even 4-CzIPN could be used as photocatalysts thanks to the favorable redox properties of these heterocycles.
Related Literature
Photoinduced work function changes by isomerization of a densely packed azobenzene-based SAM on Au: a joint experimental and theoretical study
N. Crivillers, A. Liscio, F. Di Stasio, C. Van Dyck, S. Osella, D. Cornil, S. Mian, G. M. Lazzerini, O. Fenwick, E. Orgiu, F. Reinders, S. Braun, M. Fahlman, J. Cornil, V. Palermo, F. Cacialli, P. Samorì
2011-06-22
Paper
DOI: 10.1039/C1CP20851A
Fabrication of Co3O4-reduced graphene oxide scrolls for high-performance supercapacitor electrodes
Weiwei Zhou, Tao Chen, Kim Seng Tan, Xingtao Jia, Zhiqiang Luo, Chunxiao Cong, Huanping Yang, Chang Ming Li
2011-07-07
Communication
DOI: 10.1039/C1CP21917K
Multiscale quantum mechanics/electromagnetics simulation for electronic devices
ChiYung Yam, Lingyi Meng, GuanHua Chen, Quan Chen, Ngai Wong
2011-06-10
Paper
DOI: 10.1039/C1CP20766K
Hierarchical micro/nano structures of carbon composites as anodes for microbial fuel cells
Yong Zhao
2011-07-25
Paper
DOI: 10.1039/C1CP21813A
Platinum-nanogaps for single-molecule electronics: room-temperature stability
Ferry Prins, Ahson J. Shaikh, Jan H. van Esch, Rienk Eelkema, Herre S. J. van der Zant
2011-05-09
Paper
DOI: 10.1039/C1CP20555B
Excitons in semiconducting carbon nanotubes: diameter-dependent photoluminescence spectra
Yoshihiko Kanemitsu
2011-07-07
Perspective
DOI: 10.1039/C1CP21235D
Defect processes in orthorhombic LnBaCo2O5.5 double perovskites
I. D. Seymour, A. Chroneos, J. A. Kilner, R. W. Grimes
2011-07-18
Paper
DOI: 10.1039/C1CP21471C
Bias-controlled selective excitation of vibrational modes in molecular junctions: a route towards mode-selective chemistry
Roie Volkovich, Rainer Härtle, Michael Thoss, Uri Peskin
2011-07-20
Paper
DOI: 10.1039/C1CP21161G
Modus operandi of controlled release from mesoporous matrices: a theoretical perspective
Tina Ukmar, Miran Gaberšček, Franci Merzel, Aljaž Godec
2011-07-26
Paper
DOI: 10.1039/C1CP20636B
You might also like
Compound Q&A
How should 2-Methylbenzene-1,4-diamine dihydrochloride (CAS: 615-45-2) be stored?
2-Methylbenzene-1,4-diamine dihydrochloride (CAS: 615-45-2) should be stored in ...
615-45-22-Methylbenzene-1,4-...
Compound Q&A
Is (1S,4S)-2,5-Diazabicyclo[2.2.1]heptane dihydrobromide (CAS: 132747-20-7) safe?
(1S,4S)-2,5-Diazabicyclo[2.2.1]heptane dihydrobromide is generally considered sa...
132747-20-7(1S,4S)-2,5-Diazabic...
Compound Q&A
What industries use (6-Chloropyridazin-3-YL)methanamine (CAS: 871826-15-2)?
(6-Chloropyridazin-3-YL)methanamine finds applications in the pharmaceutical ind...
871826-15-2(6-Chloropyridazin-3...
Compound Q&A
What are the main uses of 2-Fluoro-3-methylphenol (CAS: 77772-72-6)?
2-Fluoro-3-methylphenol is primarily used in the synthesis of pharmaceuticals, p...
77772-72-62-Fluoro-3-methylphe...
Compound Q&A
What precautions should be taken when handling 3-Methoxy-4-nitrobenzonitrile (CAS: 177476-75-4)?
When handling 3-Methoxy-4-nitrobenzonitrile, it is important to wear appropriate...
177476-75-43-Methoxy-4-nitroben...
Compound Q&A
What precautions should be taken when handling 1,3-Oxazolo[4,5-b]pyridine-2(3H)-thione (CAS: 211949-57-4)?
When handling 1,3-Oxazolo[4,5-b]pyridine-2(3H)-thione (CAS: 211949-57-4), it is ...
211949-57-4[1,3]Oxazolo[4,5-b]p...
Compound Q&A
What regulatory guidelines apply to 4-Ethynylbenzamide (CAS: 90347-86-7)?
4-Ethynylbenzamide (CAS: 90347-86-7) falls under various regulatory guidelines i...
90347-86-74-Ethynylbenzamide
Compound Q&A
What are the main uses of 3-(2-Ethylphenyl)-2-thioxo-4-imidazolidinone (CAS: 186822-57-1)?
3-(2-Ethylphenyl)-2-thioxo-4-imidazolidinone is primarily used as an intermediat...
186822-57-13-(2-Ethylphenyl)-2-...
Compound Q&A
What is (2-Fluoro-6-methoxyphenyl)acetic acid (CAS: 500912-19-6)?
(2-Fluoro-6-methoxyphenyl)acetic acid, also known as 4-fluoro-3-methoxybenzoic a...
500912-19-6(2-Fluoro-6-methoxyp...
Compound Q&A
What is the market or research trend for 2-[4-(Hydroxymethyl)phenoxy]ethanol (CAS: 102196-18-9)?
Market trends for 2-[4-(Hydroxymethyl)phenoxy]ethanol (CAS: 102196-18-9) indicat...
102196-18-92-[4-(Hydroxymethyl)...
Source Journal
Organic Chemistry Frontiers
CiteScore:
7.8
Self-citation Rate:
8.7%
Articles per Year:
724
Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry
Recommended Compounds
![2-Methyl-2-propanyl {3-[4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]-3-oxetanyl}carbamate structure](https://static.chemtradehub.com/structs/127/1279090-25-3-1b84.webp "2-Methyl-2-propanyl {3-[4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]-3-oxetanyl}carbamate structure")
2-Methyl-2-propanyl {3-[4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]-3-oxetanyl}carbamate
CAS Number:
1279090-25-3
Molecular Formula:
C20H30BNO5
(2S)-2-(Fluoromethyl)piperidine hydrochloride (1:1)
CAS Number:
886216-73-5
Molecular Formula:
C6H13ClFN
1-(3-Fluorophenyl)-1H-1,2,4-triazole-3-carboxylic acid
CAS Number:
1292369-51-7
Molecular Formula:
C9H6FN3O2
Recommended Suppliers
Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.