2-Methyl-2-propanyl 4-iodo-1-piperidinecarboxylate
CAS Number:
301673-14-3
Molecular Formula:
C10H18INO2
Copper-catalyzed direct decarboxylative hydrosulfonylation of aryl propiolic acids with sulfonylhydrazides leading to vinylsulfones
Literature Information
Publication Date
2015-07-10
DOI
10.1039/C5QO00212E
Impact Factor
5.281
Authors
Siyu Li, Xiang Li, Fan Yang, Yangjie Wu
View Original
Abstract
A simple and facile protocol for copper-catalyzed direct decarboxylative hydrosulfonylation of aryl propiolic acids with sulfonylhydrazides was developed, establishing an attractive approach to obtain (E)-vinylsulfones under base-free conditions. Remarkable features of this reaction include using a simple copper catalyst in air and good tolerance to aromatic and aliphatic sulfonylhydrazides.
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Source Journal
Organic Chemistry Frontiers
CiteScore:
7.8
Self-citation Rate:
8.7%
Articles per Year:
724
Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry
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