Anatase-driven charge transfer involving a spin transition in cobalt iron cyanide nanostructures

Literature Information

Publication Date 2015-07-28
DOI 10.1039/C5CP03580E
Impact Factor 3.676
Authors

Marco Giorgetti, Giuliana Aquilanti, Michela Ciabocco, Mario Berrettoni


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Abstract

A charge transfer between Fe and Co in cobalt hexacyanoferrate has been observed for the first time by anatase doping. The charge transfer, which involves a spin transition at the Co site, is supported by high-resolution XANES spectra. EXAFS evidenced a consistent change (10%) of the Co–N first shell.

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Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
CiteScore: 5.5
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