Pure and almost pure NIR emission of Tm and Tm,Yb–CeO2 under UV, X-ray and NIR up-conversion excitation: key roles of level selective antenna sensitization and charge-compensation
Literature Information
Daniel Avram, Bogdan Cojocaru, Adriana Urda, Ion Tiseanu, Mihaela Florea, Carmen Tiseanu
Herein, we report on the pure and almost pure near-infrared (NIR) emission at around 807 nm observed for Tm(Yb) (co)-doped CeO2 nanoparticles (NPs) under UV, X-ray and NIR up-conversion excitation. The optical responses are attributed to the low-lying charge-transfer of CeO2 that acts as a selective antenna sensitizer of the Tm 3H4 emission and Yb doping that lowers the local symmetry at Tm sites and introduces additional phonon modes. Selective antenna sensitization is also observed for Er/Ho (Yb) (co)-doped CeO2 NPs. To the best of our knowledge, this is a first study which correlates the down- and up-conversion emission properties of lanthanide(s)-(co) dopants with the CeO2 structure highlighting also the outstanding potential of these NPs in high-penetration tissue imaging and therapy.
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