Reply to the ‘Comment on “Charge Transfer to Solvent Dynamics in Iodide Aqueous Solution Studied at Ionization Threshold”’ by A. Lübcke and H.-H. Ritze, Phys. Chem. Chem. Phys., 2015, 17, DOI: 10.1039/C5CP00346F

Literature Information

Publication Date 2015-06-10
DOI 10.1039/C5CP01804H
Impact Factor 3.676
Authors

Alexander Kothe, Martin Wilke, Alexandre Moguilevski, Nicholas Engel, Bernd Winter, Igor Yu. Kiyan


View Original

Abstract

The role of experimental conditions in the study of the early-time charge transfer to solvent dynamics in iodide aqueous solution is revised. Under the short (∼50 fs) laser pulse regime of the current experiment, the presence of the pump–probe cross-correlation signal in the transient photoelectron spectra can be ruled out due to the much larger time scale of the electron-transfer dynamics. The ratio of the ionization yields from different initial states of iodide and water is argued to be dependent on the electron kinetic energy, and to be influenced by the presence of a bound resonance state above the vacuum threshold. Re-evaluation of our experimental data reassures the presence of an intermediate state in the charge-transfer process, initiated by electronic excitation into the continuum spectrum.

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Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
CiteScore: 5.5
Self-citation Rate: 10.3%
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Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

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