A simple approach to hybrid inorganic–organic step-growth hydrogels with scalable control of physicochemical properties and biodegradability

Literature Information

Publication Date 2015-01-30
DOI 10.1039/C4PY01789G
Impact Factor 5.582
Authors

F. Alves, I. Nischang


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Abstract

We prepared new and scalable, hybrid inorganic–organic step-growth hydrogels with polyhedral oligomeric silsesquioxane (POSS) network knot construction elements and hydrolytically degradable poly(ethylene glycol) (PEG) di-ester macromonomers by in situ radical-mediated thiol–ene photopolymerization. The physicochemical properties of the gels are fine-tailored over orders of magnitude including functionalization of their interior, a hierarchical gel structure, and biodegradability.

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