In situ and readily prepared metal catalysts and initiators for living cationic polymerization of isobutyl vinyl ether: dual-purpose salphen as a ligand framework for ZrCl4 and an initiating proton source
Literature Information
Publication Date
2014-09-02
DOI
10.1039/C4PY01012D
Impact Factor
5.582
Authors
Sensho Kigoshi, Arihiro Kanazawa, Shokyoku Kanaoka, Sadahito Aoshima
View Original
Abstract
A salphen complex [salphen = N,N′-o-phenylene-bis(3,5-di-tert-butyl-salicylidene-imine)], synthesized in situ by mixing a salphen ligand with a metal chloride is shown to be an effective catalyst in cationic polymerization for the first time. Furthermore, the salphen/ZrCl4 system induced the living cationic polymerization of isobutyl vinyl ether in toluene at 0 °C with quantitative initiation from HCl simultaneously generated upon the complex formation.
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Source Journal
Polymer Chemistry
CiteScore:
8.6
Self-citation Rate:
7.3%
Articles per Year:
457
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Recommended Compounds
Oxalic acid compound with cyclohexylsulfamothioic O-acid (11)
CAS Number:
31895-22-4
Molecular Formula:
C7H13NO4S3
![N-[(E)-Phenylmethylene]benzenesulfonamide structure](https://static.chemtradehub.com/structs/139/13909-34-7-8167.webp "N-[(E)-Phenylmethylene]benzenesulfonamide structure")
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