Supramolecular polymerization of supramonomers: a way for fabricating supramolecular polymers
Literature Information
Publication Date
2014-07-16
DOI
10.1039/C4PY00942H
Impact Factor
5.582
Authors
Qiao Song, Fei Li, Xinxin Tan, Liulin Yang, Zhiqiang Wang, Xi Zhang
View Original
Abstract
This communication describes a new method of fabricating supramolecular polymers through supramolecular polymerization of supramonomers. To mix building blocks of Phe-Gly-Gly linked with an azobenzene group and cucurbit[8]uril (CB[8]) in a molar ratio of 2 : 1 in aqueous solutions, supramonomers were obtained by host–guest interaction between tripeptide and CB[8]. Then supramolecular polymers were formed spontaneously by mixing the supramonomers with bis-β-cyclodextrins in a molar ratio of 1 : 1 in an aqueous solution through noncovalent host–guest complexation of the azobenzene group and β-cyclodextrin. Considering that various noncovalent interactions can be used to drive the formation of supramonomers and the supramolecular polymerization of the supramonomers, this study can enrich the methodology of fabricating supramolecular polymers.
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Source Journal
Polymer Chemistry
CiteScore:
8.6
Self-citation Rate:
7.3%
Articles per Year:
457
Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.
Recommended Compounds
N,N-Dimethyl-5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-2-pyrimidinamine
CAS Number:
1032759-30-0
Molecular Formula:
C12H20BN3O2
![4-[(3-Chloro-2-fluorophenyl)amino]-7-methoxy-6-quinazolinyl acetate structure](https://static.chemtradehub.com/structs/740/740081-22-5-f58f.webp "4-[(3-Chloro-2-fluorophenyl)amino]-7-methoxy-6-quinazolinyl acetate structure")
4-[(3-Chloro-2-fluorophenyl)amino]-7-methoxy-6-quinazolinyl acetate
CAS Number:
740081-22-5
Molecular Formula:
C17H13ClFN3O3
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