Synthesis of well-controlled graft polymers by living anionic polymerization towards exact graft polymers

Literature Information

Publication Date 2014-07-21
DOI 10.1039/C4PY00584H
Impact Factor 5.582
Authors

Shotaro Ito, Raita Goseki, Takashi Ishizone


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Abstract

This article reviews the synthesis of well-controlled graft polymers by living anionic polymerization towards exact graft polymers. The structure of a graft polymer is defined by the following three parameters: (1) molecular weight of the main chain, (2) molecular weight of the graft chain, and (3) placement of the graft chain. Based on these three parameters, the extent of the structural control of the graft polymers synthesized so far is described. Finally, the recently synthesized exact graft (co)polymers by stepwise iterative methodologies are introduced. In their structures, the three parameters are perfectly controlled.

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Polymer Chemistry

Polymer Chemistry
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