Extending the range of switchable-hydrophilicity solvents

Literature Information

Publication Date 2015-01-09
DOI 10.1039/C4CP05313C
Impact Factor 3.676
Authors

Jeremy Durelle, Jesse R. Vanderveen, Yi Quan, Courtney B. Chalifoux, Julia E. Kostin, Philip G. Jessop


View Original

Abstract

A switchable-hydrophilicity solvent (SHS) is a solvent that in one state forms a biphasic mixture with water but can be reversibly switched to another state that is miscible with water. All of the amine SHSs that we have reported previously lie within a particular basicity and hydrophilicity range (9.5 < pKaH < 11 and 1.0 < log Kow < 2.5, respectively). We report an extension of this range by altering the pressure of CO2 as well as the water : SHS volume ratio used in the process. Increasing the pressure of CO2 and/or the water : amine volume ratio allows some amines with pKaH < 9.5 or log Kow > 2.5 to function as SHSs.

Related Literature

Acceptor doping in the proton conductor SrZrO3

Leigh Weston, A. Janotti, X. Y. Cui, C. Stampfl, C. G. Van de Walle

2017-04-12 Paper

DOI: 10.1039/C7CP01471F

Ultrathin CoOx-modified hematite with low onset potential for solar water oxidation

Chun Du, Jun Wang, Xiao Liu, Jie Yang, Kun Cao, Yanwei Wen

2017-05-22 Paper

DOI: 10.1039/C7CP01588G

Contents list

Front/Back Matter

DOI: 10.1039/C7CP90121F

Electrochemical reduction of CO2 on graphene supported transition metals – towards single atom catalysts

Haiying He, Yesukhei Jagvaral

2017-04-10 Paper

DOI: 10.1039/C7CP00915A

Study of antiradical mechanisms with dihydroxybenzenes using reaction force and reaction electronic flux

Cristina Ortega-Moo, Rocio Durán, Bárbara Herrera, Soledad Gutiérrez-Oliva, Rubicelia Vargas

2017-05-08 Paper

DOI: 10.1039/C7CP01304C

Back cover

Cover

DOI: 10.1039/C7CP90141K

From oxidative degradation to direct oxidation: size regimes in the consecutive reaction of cationic tantalum clusters with dioxygen

J. F. Eckhard, D. Neuwirth, M. Tschurl, U. Heiz

2017-04-04 Paper

DOI: 10.1039/C7CP01293D

Contents list

Front/Back Matter

DOI: 10.1039/C7CP90102J

Phonons spreading from laser-heated gold nanoparticle array accelerate diffusion of excitons in an underlying polythiophene thin film

David Rais, Miroslav Menšík, Bartosz Paruzel, Dharmalingam Kurunthu, Jiří Pfleger

2017-03-24 Paper

DOI: 10.1039/C7CP00286F

Structural control of side-chain chromophores to achieve highly efficient electro-optic activity

Zhuo Chen, Jialei Liu, Hongyan Xiao, Zhen Zhen, Xinhou Liu

2017-03-31 Paper

DOI: 10.1039/C7CP01582H

You might also like

Compound Q&A

How should waste containing N-Methoxy-N-methyl-1,3-thiazole-5-carboxamide (CAS: 898825-89-3) be handled?

Waste containing N-Methoxy-N-methyl-1,3-thiazole-5-carboxamide (CAS: 898825-89-3...

898825-89-3N-Methoxy-N-methyl-1...
Compound Q&A

How should N-(4-Biphenylyl)dibenzo[b,d]furan-4-amine (CAS: 1318338-47-4) be stored?

N-(4-Biphenylyl)dibenzo[b,d]furan-4-amine should be stored in a tightly sealed c...

1318338-47-4N-(4-Biphenylyl)dibe...
Compound Q&A

What is the market or research trend for 3-Acetamido-5-amino-2,4,6-triiodobenzoic acid (CAS: 1713-07-1)?

The market for 3-Acetamido-5-amino-2,4,6-triiodobenzoic acid (CAS: 1713-07-1) is...

1713-07-13-Acetamido-5-amino-...
Compound Q&A

How should Benzyl 2-O-acetyl-3,4,6-tri-O-benzyl-beta-D-galactopyranoside (CAS: 61820-03-9) be stored?

Benzyl 2-O-acetyl-3,4,6-tri-O-benzyl-beta-D-galactopyranoside (CAS: 61820-03-9) ...

61820-03-9Benzyl 2-O-acetyl-3,...
Compound Q&A

What regulatory guidelines apply to 2-Ethylpiperazine dihydrochloride (CAS: 438050-52-3)?

2-Ethylpiperazine dihydrochloride (CAS: 438050-52-3) is regulated under the Glob...

438050-52-32-Ethylpiperazine di...
Compound Q&A

What regulatory guidelines apply to 1,1'-[1,3-Phenylenebis(methylene)]bis(3-methyl-1H-pyrrole-2,5-dione) (CAS: 119462-56-5)?

1,1'-[1,3-Phenylenebis(methylene)]bis(3-methyl-1H-pyrrole-2,5-dione) (CAS: 11946...

119462-56-51,1'-[1,3-Phenyleneb...
Compound Q&A

Are there alternatives to 5-Fluoro-2-(1-pyrrolidinyl)pyridine (CAS: 1287217-79-1) in synthesis?

Several alternatives can be used in the synthesis of 5-Fluoro-2-(1-pyrrolidinyl)...

1287217-79-15-Fluoro-2-(1-pyrrol...
Compound Q&A

What precautions should be taken when handling 6-Bromoimidazo[1,2-a]pyridin-8-amine (CAS: 676371-00-9)?

When handling 6-Bromoimidazo[1,2-a]pyridin-8-amine, it is important to wear appr...

676371-00-96-Bromoimidazo[1,2-a...
Compound Q&A

Are there alternatives to (2S,4R)-4-(4-Nitrobenzyl)pyrrolidine-2-carboxylic acid hydrochloride (CAS: 1049740-22-8) in synthesis?

Alternatives to (2S,4R)-4-(4-Nitrobenzyl)pyrrolidine-2-carboxylic acid hydrochlo...

1049740-22-8(2S,4R)-4-(4-Nitrobe...

Source Journal

Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
CiteScore: 5.5
Self-citation Rate: 10.3%
Articles per Year: 3036

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

Recommended Compounds

Recommended Suppliers

Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.