Charge transfer to solvent dynamics in iodide aqueous solution studied at ionization threshold

Literature Information

Publication Date 2014-11-27
DOI 10.1039/C4CP02482F
Impact Factor 3.676
Authors

Alexander Kothe, Martin Wilke, Alexandre Moguilevski, Nicholas Engel, Bernd Winter, Igor Yu. Kiyan


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Abstract

We explore the early-time electronic relaxation in NaI aqueous solution exposed to a short UV laser pulse. Rather than initiating the charge transfer reaction by resonant photoexcitation of iodide, in the present time-resolved photoelectron spectroscopy study the charge-transfer-to-solvent (CTTS) states are populated via electronic excitation above the vacuum level. By analyzing the temporal evolution of electron yields from ionization of two transient species, assigned to CTTS and its first excited state, we determine both their ultrafast population and relaxation dynamics. Comparison with resonant-excitation studies shows that the highly excited initial states exhibit similar relaxation characteristics as found for resonant excitation. Implications for structure and dynamical response of the hydration cage are discussed.

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Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
CiteScore: 5.5
Self-citation Rate: 10.3%
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