New chromone based photoinitiators for polymerization reactions under visible light
Literature Information
Publication Date
2013-05-23
DOI
10.1039/C3PY00536D
Impact Factor
5.582
Authors
Mohamad-Ali Tehfe, Frédéric Dumur, Pu Xiao, Bernadette Graff, Fabrice Morlet-Savary, Jean-Pierre Fouassier, Didier Gigmes, Jacques Lalevée
View Original
Abstract
Novel photoinitiators derived from a chromone structure are proposed for the free radical polymerization of acrylates and the free radical promoted cationic polymerization of epoxides upon exposure to a 457 nm laser diode and even under soft irradiation conditions (blue LED bulb at 462 nm and halogen lamp). Good polymerization profiles are obtained. These original dyes exhibit a push–pull molecular character as revealed by MO calculations. The initiation mechanisms are analyzed through ESR, fluorescence and laser flash photolysis experiments.
Related Literature
The photodissociation of NO2 by visible and ultraviolet light
Iain Wilkinson, Ivan Anton Garcia, Benjamin J. Whitaker, Jean-Benoît Hamard, Valérie Blanchet
2010-11-16
Paper
DOI: 10.1039/C0CP01551B
Formation dynamics and nature of tryptophan's primary photoproduct in aqueous solution
J. Léonard, D. Sharma, B. Szafarowicz, K. Torgasin, S. Haacke
2010-08-16
Paper
DOI: 10.1039/C0CP00615G
Mitochondrial biofuel cells: expanding fuel diversity to amino acids
Dushyant Bhatnagar, Shuai Xu, Caitlin Fischer, Robert L. Arechederra, Shelley D. Minteer
2010-11-10
Perspective
DOI: 10.1039/C0CP01362E
On the role of mercury in the non-covalent stabilisation of consecutive U–HgII–U metal-mediated nucleic acid base pairs: metallophilic attraction enters the world of nucleic acids
Ladislav Benda, Michal Straka, Yoshiyuki Tanaka, Vladimír Sychrovský
2010-11-03
Communication
DOI: 10.1039/C0CP01534B
Using one-step perturbation to predict the folding equilibrium of differently stereochemically substituted β-peptides
Wilfred F. van Gunsteren
2010-10-29
Paper
DOI: 10.1039/C0CP00833H
Multidimensional steric effect for the XeF* (B, C) formation in the oriented Xe* (3P2, MJ = 2) + oriented NF3 reaction
H. Ohoyama
2010-10-21
Paper
DOI: 10.1039/C0CP00648C
Compact microcubic structures platform based on self-assembly Prussian blue nanoparticles with highly tuneable conductivity
Maria Guix
2010-10-26
Paper
DOI: 10.1039/C0CP00960A
You might also like
Compound Q&A
What are the main uses of 4-Nitrophenyl phosphate disodium salt hexahydrate (CAS: 333338-18-4)?
4-Nitrophenyl phosphate disodium salt hexahydrate is primarily used as a substra...
333338-18-44-Nitrophenyl phosph...
Compound Q&A
What are the main uses of 2-(Trifluoromethyl)-1,3-oxazole-4-carboxylic Acid (CAS: 1060816-01-4)?
2-(Trifluoromethyl)-1,3-oxazole-4-carboxylic Acid (CAS: 1060816-01-4) is widely ...
1060816-01-42-(Trifluoromethyl)-...
Compound Q&A
How should 2-Fluoro-4-biphenylcarboxylic acid (CAS: 137045-30-8) be stored?
2-Fluoro-4-biphenylcarboxylic acid should be stored in a cool, dry place at room...
137045-30-82-Fluoro-4-biphenylc...
Compound Q&A
What industries use Prednisolone-21-Carboxylic Acid (CAS: 61549-70-0)?
Prednisolone-21-Carboxylic Acid is primarily used in the pharmaceutical industry...
61549-70-0Prednisolone-21-Carb...
Compound Q&A
How should 4-(Hydrazinomethyl)-1,2,3-benzenetriol (CAS: 3614-72-0) be stored?
4-(Hydrazinomethyl)-1,2,3-benzenetriol (CAS: 3614-72-0) should be stored in a co...
3614-72-04-(Hydrazinomethyl)-...
Compound Q&A
What industries use 4-Amino-1-methyl-1H-pyrazole-5-carboxylic acid hydrochloride (CAS: 92534-70-8)?
4-Amino-1-methyl-1H-pyrazole-5-carboxylic acid hydrochloride (CAS: 92534-70-8) i...
92534-70-84-Amino-1-methyl-1H-...
Compound Q&A
What regulatory guidelines apply to dehydropachymic acid (CAS: 77012-31-8)?
Dehydropachymic acid (CAS: 77012-31-8) is regulated by various agencies. It fall...
77012-31-8Dehydropachymic acid
Compound Q&A
What is the market or research trend for 6-[(2,2-Dimethylpropanoyl)amino]nicotinic acid (CAS: 898561-66-5)?
The market and research trends for 6-[(2,2-Dimethylpropanoyl)amino]nicotinic aci...
898561-66-56-[(2,2-Dimethylprop...
Compound Q&A
How should 1,10-Phenanthroline-2,9-dicarbaldehyde (CAS: 57709-62-3) be stored?
1,10-Phenanthroline-2,9-dicarbaldehyde should be stored in a cool, dry place awa...
57709-62-31,10-Phenanthroline-...
Compound Q&A
How is 5-Carbamoyl-11-oxo-10,11-dihydro-5H-dibenzo[b,f]azepin-10-yl acetate (CAS: 113952-21-9) typically synthesized?
5-Carbamoyl-11-oxo-10,11-dihydro-5H-dibenzo[b,f]azepin-10-yl acetate can be synt...
113952-21-95-Carbamoyl-11-oxo-1...
Source Journal
Polymer Chemistry
CiteScore:
8.6
Self-citation Rate:
7.3%
Articles per Year:
457
Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.
Recommended Compounds
Recommended Suppliers
Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.