Photoinduced polyaddition of multifunctional azides and alkynes
Literature Information
Publication Date
2013-04-24
DOI
10.1039/C3PY00356F
Impact Factor
5.582
Authors
Peter Burtscher, Norbert Moszner
View Original
Abstract
The photoinduced copper(I)-catalyzed polymerization of multifunctional azides and alkynes is facilitated by the photoreduction of copper(II) acetate generating copper(I) ions without using any additional photoinitiator. The polymerization can only be carried out in solution using at least 15 wt% of methanol. Depending on the catalyst concentration quantitative monomer conversions can be achieved allowing the determination of the mechanical properties. The bifunctional system consisting of a di-azide and di-alkyne exhibited the highest Young's modulus value of 1600 MPa.
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Source Journal
Polymer Chemistry
CiteScore:
8.6
Self-citation Rate:
7.3%
Articles per Year:
457
Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.
Recommended Compounds
(R)-2-(Methylamino)propanoic acid hydrochloride
CAS Number:
1155878-14-0
Molecular Formula:
C4H10ClNO2
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