Living radical polymerization of vinyl acetate and methyl acrylate mediated by Co(Salen*) complexes
Literature Information
Publication Date
2013-03-14
DOI
10.1039/C3PY00282A
Impact Factor
5.582
Authors
Chei-Ming Liao, Ching-Chun Hsu, Fu-Sheng Wang, Bradford B. Wayland, Chi-How Peng
View Original
Abstract
Vinyl acetate and methyl acrylate living radical polymerization were successfully mediated by cobalt(II) Salen* complexes. Living characters of the polymerization are demonstrated by the linear increase in molecular weight with conversion, low polydispersity (1.14–1.27), and the formation of block copolymers. The equilibrium between cobalt(II) and organo-cobalt(III) species in methyl acrylate polymerization was followed by UV-vis spectroscopy and the equilibrium constant was determined to be 2.4 × 107 M−1.
Related Literature
A facile synthesis of single-crystal mullite nanobelts
Chuanbao Cao, Xu Xiang, Hesun Zhu
2004-09-24
Communication
DOI: 10.1039/B409087J
Self-oriented pseudoisocyanine J-aggregates in solution
Ken Takazawa, Yasutaka Kitahama, Yasuyuki Kimura
2004-09-07
Communication
DOI: 10.1039/B409690H
A first oxalamidino complex of samarium via reduction-coupling of carbodiimine: synthesis and molecular structure of [η4-C2(NR)4][(MeC5H4)2Sm(HMPA)]2·2THF (R = Pri, Cy)
Mingyu Deng, Yingmin Yao, Yong Zhang
2004-10-15
Communication
DOI: 10.1039/B410599K
Stereoelective polymerization of d,l-lactide using N-heterocyclic carbene based compounds
Tryg R. Jensen, Laurie E. Breyfogle, Marc A. Hillmyer, William B. Tolman
2004-09-08
Communication
DOI: 10.1039/B405362A
A novel strategy for the preparation of arylhydroxylamines: chemoselective reduction of aromatic nitro compounds using bakers' yeast
Feng Li, Jingnan Cui, Rong Zhang
2004-09-07
Communication
DOI: 10.1039/B408566C
Mechanism of hydrogen transfer to imines from a hydroxycyclopentadienyl ruthenium hydride. Support for a stepwise mechanism
Joseph S. M. Samec, Alida H. Éll, Jan-E. Bäckvall
2004-10-06
Communication
DOI: 10.1039/B410698A
Supramolecular isomerism in spin crossover networks with aurophilic interactions
Ana Galet, M. Carmen Muñoz, Víctor Martínez, José Antonio Real
2004-09-07
Communication
DOI: 10.1039/B409974E
Synthesis and reactivity of triethylborane adduct of N-heterocyclic carbene: versatile synthons for synthesis of N-heterocyclic carbene complexes
Yoshitaka Yamaguchi, Taigo Kashiwabara, Kenichi Ogata, Yumiko Miura, Yoshiyuki Nakamura, Kimiko Kobayashi, Takashi Ito
2004-08-20
Communication
DOI: 10.1039/B405459H
A very large Rh–Rh bond shortening on excitation of the [Rh2(1,8-diisocyano-p-menthane)4]2+ ion by time-resolved synchrotron X-ray diffraction
Yu-Sheng Chen, Tim Graber
2004-08-19
Communication
DOI: 10.1039/B409463H
A new organic superconductor β-(meso-DMBEDT-TTF)2PF6
Tadashi Kawamoto, Takehiko Mori, Hiroshi Moriyama, Yutaka Nishio, Koji Kajita
2004-09-21
Communication
DOI: 10.1039/B409631B
You might also like
Compound Q&A
What is 1-(2,4,6-Trifluorophenyl)ethanol (CAS: 1250113-83-7)?
1-(2,4,6-Trifluorophenyl)ethanol is an organic compound with the CAS number 1250...
1250113-83-71-(2,4,6-Trifluoroph...
Compound Q&A
Is 1-(2,4-Dimethoxybenzyl)-4-(hydroxymethyl)-2-pyrrolidinone (CAS: 919111-34-5) safe?
1-(2,4-Dimethoxybenzyl)-4-(hydroxymethyl)-2-pyrrolidinone (CAS: 919111-34-5) is ...
919111-34-51-(2,4-Dimethoxybenz...
Compound Q&A
What are the physical and chemical properties of (7S,15R)-6β,15-Diacetoxy-7α,20-epoxy-7-hydroxykaura-2,16-dien-1-one (CAS: 51419-51-3)?
(7S,15R)-6β,15-Diacetoxy-7α,20-epoxy-7-hydroxykaura-2,16-dien-1-one is a crystal...
51419-51-3(7S,15R)-6β,15-Diace...
Compound Q&A
What regulatory guidelines apply to rac-ethyl (1r,4r)-4-hydroxycyclohexane-1-carboxylate, trans (CAS: 3618-04-0)?
The compound rac-ethyl (1r,4r)-4-hydroxycyclohexane-1-carboxylate, trans (CAS: 3...
3618-04-0rac-ethyl (1r,4r)-4-...
Compound Q&A
What is the market or research trend for 2-(2,4-Difluorophenoxy)-3-nitropyridine (CAS: 175135-62-3)?
The market for 2-(2,4-Difluorophenoxy)-3-nitropyridine (CAS: 175135-62-3) is cur...
175135-62-32-(2,4-Difluoropheno...
Compound Q&A
What are the main uses of 6-Diazo-5-oxo-L-norleucine (CAS: 157-03-9)?
The main uses of 6-Diazo-5-oxo-L-norleucine (CAS: 157-03-9) include research in ...
157-03-96-Diazo-5-oxo-L-norl...
Compound Q&A
What precautions should be taken when handling 2-Aminoethyl-mono-amide-DOTA-tris(tBu ester) (CAS: 173308-19-5)?
When handling 2-Aminoethyl-mono-amide-DOTA-tris(tBu ester) (CAS: 173308-19-5), i...
173308-19-52-Aminoethyl-mono-am...
Compound Q&A
How is 5-Methylimidazo[1,2-a]pyridine-3-carbaldehyde (CAS: 178488-37-4) typically synthesized?
5-Methylimidazo[1,2-a]pyridine-3-carbaldehyde (CAS: 178488-37-4) can be synthesi...
178488-37-45-Methylimidazo[1,2-...
Compound Q&A
Are there alternatives to 2,4,6-Trihydroxyisophthalaldehyde (CAS: 4396-13-8) in synthesis?
There are alternative reagents that can be used in the synthesis of 2,4,6-Trihyd...
4396-13-82,4,6-Trihydroxyisop...
Compound Q&A
What is (2Z)-3-(5-Fluoro-1H-indol-3-yl)-2-sulfanylacrylic acid (CAS: 179461-52-0)?
(2Z)-3-(5-Fluoro-1H-indol-3-yl)-2-sulfanylacrylic acid is a chemical compound wi...
179461-52-0(2Z)-3-(5-Fluoro-1H-...
Source Journal
Polymer Chemistry
CiteScore:
8.6
Self-citation Rate:
7.3%
Articles per Year:
457
Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.
Recommended Compounds
Recommended Suppliers
Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.