Living radical polymerization of vinyl acetate and methyl acrylate mediated by Co(Salen*) complexes
Literature Information
Chei-Ming Liao, Ching-Chun Hsu, Fu-Sheng Wang, Bradford B. Wayland, Chi-How Peng
Vinyl acetate and methyl acrylate living radical polymerization were successfully mediated by cobalt(II) Salen* complexes. Living characters of the polymerization are demonstrated by the linear increase in molecular weight with conversion, low polydispersity (1.14–1.27), and the formation of block copolymers. The equilibrium between cobalt(II) and organo-cobalt(III) species in methyl acrylate polymerization was followed by UV-vis spectroscopy and the equilibrium constant was determined to be 2.4 × 107 M−1.
Related Literature
Polymerization of n-butyl acrylate with high concentration of a chain transfer agent (CBr4): detailed characterization and impact on branching
A. Agirre, J. I. Santos, A. Etxeberria, V. Sauerland, J. R. Leiza
DOI: 10.1039/C2PY21123H
Catalytic Y-tailed amphiphilic homopolymers – aqueous nanoreactors for high activity, low loading SCS pincer catalysts
Joseph P. Patterson, Pepa Cotanda, Elizabeth G. Kelley, Adam O. Moughton, Annhelen Lu, Thomas H. Epps, III, Rachel K. O'Reilly
DOI: 10.1039/C3PY21137A
Supramolecular micelles with dual temperature and redox responses for multi-controlled drug release
Hui Zou, Wen Guo, Tianxiang Shen
DOI: 10.1039/C3PY00211J
UV-induced functionalization of poly(divinylbenzene) nanoparticlesvia efficient [2 + 2]-photocycloadditions
Anitha Ethirajan, Matthias Conradi, Kayte Ranieri, Bert Conings, Hans-Gerd Boyen, Tanja Junkers
DOI: 10.1039/C3PY00427A
SET-LRP synthesis of novel polyallene-based well-defined amphiphilic graft copolymers in acetone
Guolin Lu, Yongjun Li, Hao Guo, Weiyuan Du, Xiaoyu Huang
DOI: 10.1039/C3PY00145H
Facile synthesis of thermal-responsive P(NIPAM-S)/SiO2 hybrid hollow spheres and their controllable release properties for fragrance
Liqin Liu, Yuyao Xie, Limin Wu
DOI: 10.1039/C3PY00186E
Synthesis of 1,4-polybutadiene-g-poly(ethylene oxide) via the macromonomer approach by ROMP
Dao Le, Véronique Montembault, Sagrario Pascual, Floraine Collette, Valérie Héroguez, Laurent Fontaine
DOI: 10.1039/C3PY21103G
Stainless steel surfaces with thiol-terminated hyperbranched polymers for functionalization viathiol-based chemistry
Wen Jing Yang, Koon-Gee Neoh, En-Tang Kang, Serena Lay-Ming Teo, Daniel Rittschof
DOI: 10.1039/C3PY00009E
You might also like
What is 1-(2,4,6-Trifluorophenyl)ethanol (CAS: 1250113-83-7)?
1-(2,4,6-Trifluorophenyl)ethanol is an organic compound with the CAS number 1250...
Is 1-(2,4-Dimethoxybenzyl)-4-(hydroxymethyl)-2-pyrrolidinone (CAS: 919111-34-5) safe?
1-(2,4-Dimethoxybenzyl)-4-(hydroxymethyl)-2-pyrrolidinone (CAS: 919111-34-5) is ...
What are the physical and chemical properties of (7S,15R)-6β,15-Diacetoxy-7α,20-epoxy-7-hydroxykaura-2,16-dien-1-one (CAS: 51419-51-3)?
(7S,15R)-6β,15-Diacetoxy-7α,20-epoxy-7-hydroxykaura-2,16-dien-1-one is a crystal...
What regulatory guidelines apply to rac-ethyl (1r,4r)-4-hydroxycyclohexane-1-carboxylate, trans (CAS: 3618-04-0)?
The compound rac-ethyl (1r,4r)-4-hydroxycyclohexane-1-carboxylate, trans (CAS: 3...
What is the market or research trend for 2-(2,4-Difluorophenoxy)-3-nitropyridine (CAS: 175135-62-3)?
The market for 2-(2,4-Difluorophenoxy)-3-nitropyridine (CAS: 175135-62-3) is cur...
What are the main uses of 6-Diazo-5-oxo-L-norleucine (CAS: 157-03-9)?
The main uses of 6-Diazo-5-oxo-L-norleucine (CAS: 157-03-9) include research in ...
What precautions should be taken when handling 2-Aminoethyl-mono-amide-DOTA-tris(tBu ester) (CAS: 173308-19-5)?
When handling 2-Aminoethyl-mono-amide-DOTA-tris(tBu ester) (CAS: 173308-19-5), i...
How is 5-Methylimidazo[1,2-a]pyridine-3-carbaldehyde (CAS: 178488-37-4) typically synthesized?
5-Methylimidazo[1,2-a]pyridine-3-carbaldehyde (CAS: 178488-37-4) can be synthesi...
Are there alternatives to 2,4,6-Trihydroxyisophthalaldehyde (CAS: 4396-13-8) in synthesis?
There are alternative reagents that can be used in the synthesis of 2,4,6-Trihyd...
What is (2Z)-3-(5-Fluoro-1H-indol-3-yl)-2-sulfanylacrylic acid (CAS: 179461-52-0)?
(2Z)-3-(5-Fluoro-1H-indol-3-yl)-2-sulfanylacrylic acid is a chemical compound wi...
Source Journal
Polymer Chemistry

Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.














