Stereoelective polymerization of d,l-lactide using N-heterocyclic carbene based compounds
Literature Information
Publication Date
2004-09-08
DOI
10.1039/B405362A
Impact Factor
6.222
Authors
Tryg R. Jensen, Laurie E. Breyfogle, Marc A. Hillmyer, William B. Tolman
View Original
Abstract
A new Zn alkoxide catalyst supported by an N-heterocyclic carbene rapidly polymerizes D,L-lactide (D,L-LA) to heterotactic enriched poly(lactide) (PLA), while the free carbene and analogs instead yield highly isotactic enriched PLA.
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Source Journal
Chemical Communications
CiteScore:
8.6
Self-citation Rate:
4.7%
Articles per Year:
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