A first oxalamidino complex of samarium via reduction-coupling of carbodiimine: synthesis and molecular structure of [η4-C2(NR)4][(MeC5H4)2Sm(HMPA)]2·2THF (R = Pri, Cy)

Literature Information

Publication Date 2004-10-15
DOI 10.1039/B410599K
Impact Factor 6.222
Authors

Mingyu Deng, Yingmin Yao, Yong Zhang


View Original

Abstract

Treatment of the THF solution of (MeC5H4)2Sm(THF) with an equivalent of carbodiimine [RNCNR] (R = Pri or Cy; Cy = cyclohexyl) in the presence of an equivalent of hexamethylphosphoric triamide (HMPA) at room temperature gives, via a reduction-coupling reaction of carbodiimine, the corresponding bimetallic oxalamidino complex of samarium [η4-C2(NR)4][(MeC5H4)2Sm(HMPA)]2·2THF.

Related Literature

Brushed polyethylene glycol and phosphorylcholine for grafting nanoparticles against protein binding

Bo Wang, Thomas Blin, Aleksandr Käkinen, Xinwei Ge, Emily H. Pilkington, John F. Quinn, Michael R. Whittaker, Pu Chun Ke, Feng Ding

2016-09-23 Communication

DOI: 10.1039/C6PY01480A

Artificial membranes with selective nanochannels for protein transport

B. Sutisna, G. Polymeropoulos, E. Mygiakis, V. Musteata, K.-V. Peinemann, D.-M. Smilgies, N. Hadjichristidis, S. P. Nunes

2016-09-05 Paper

DOI: 10.1039/C6PY01401A

Regioselective cross metathesis for block and heterotelechelic polymer synthesis

Madalyn R. Radlauer, Megan E. Matta, Marc A. Hillmyer

2016-09-27 Paper

DOI: 10.1039/C6PY01231K

Contents list

Front/Back Matter

DOI: 10.1039/C5PY90029H

pH-Triggered release of gemcitabine from polymer coated nanodiamonds fabricated by RAFT polymerization and copper free click chemistry

Haiwang Lai, Mingxia Lu, Hongxu Lu, Martina H. Stenzel, Pu Xiao

2016-08-10 Paper

DOI: 10.1039/C6PY01188H

Synthesis and photophysical and supramolecular study of π-conjugated (diethylene glycol methyl ether) benzoateethynylene oligomers and polymers

D. Meza, E. Arias, I. Moggio, J. Romero, J. M. Mata, R. M. Jiménez-Barrera, R. F. Ziolo, O. Rodríguez, M. Ottonelli

2014-12-15 Paper

DOI: 10.1039/C4PY01516A

You might also like

Compound Q&A

What is 1-(2,4,6-Trifluorophenyl)ethanol (CAS: 1250113-83-7)?

1-(2,4,6-Trifluorophenyl)ethanol is an organic compound with the CAS number 1250...

1250113-83-71-(2,4,6-Trifluoroph...
Compound Q&A

Is 1-(2,4-Dimethoxybenzyl)-4-(hydroxymethyl)-2-pyrrolidinone (CAS: 919111-34-5) safe?

1-(2,4-Dimethoxybenzyl)-4-(hydroxymethyl)-2-pyrrolidinone (CAS: 919111-34-5) is ...

919111-34-51-(2,4-Dimethoxybenz...
Compound Q&A

What are the physical and chemical properties of (7S,15R)-6β,15-Diacetoxy-7α,20-epoxy-7-hydroxykaura-2,16-dien-1-one (CAS: 51419-51-3)?

(7S,15R)-6β,15-Diacetoxy-7α,20-epoxy-7-hydroxykaura-2,16-dien-1-one is a crystal...

51419-51-3(7S,15R)-6β,15-Diace...
Compound Q&A

What regulatory guidelines apply to rac-ethyl (1r,4r)-4-hydroxycyclohexane-1-carboxylate, trans (CAS: 3618-04-0)?

The compound rac-ethyl (1r,4r)-4-hydroxycyclohexane-1-carboxylate, trans (CAS: 3...

3618-04-0rac-ethyl (1r,4r)-4-...
Compound Q&A

What is the market or research trend for 2-(2,4-Difluorophenoxy)-3-nitropyridine (CAS: 175135-62-3)?

The market for 2-(2,4-Difluorophenoxy)-3-nitropyridine (CAS: 175135-62-3) is cur...

175135-62-32-(2,4-Difluoropheno...
Compound Q&A

What are the main uses of 6-Diazo-5-oxo-L-norleucine (CAS: 157-03-9)?

The main uses of 6-Diazo-5-oxo-L-norleucine (CAS: 157-03-9) include research in ...

157-03-96-Diazo-5-oxo-L-norl...
Compound Q&A

What precautions should be taken when handling 2-Aminoethyl-mono-amide-DOTA-tris(tBu ester) (CAS: 173308-19-5)?

When handling 2-Aminoethyl-mono-amide-DOTA-tris(tBu ester) (CAS: 173308-19-5), i...

173308-19-52-Aminoethyl-mono-am...
Compound Q&A

How is 5-Methylimidazo[1,2-a]pyridine-3-carbaldehyde (CAS: 178488-37-4) typically synthesized?

5-Methylimidazo[1,2-a]pyridine-3-carbaldehyde (CAS: 178488-37-4) can be synthesi...

178488-37-45-Methylimidazo[1,2-...
Compound Q&A

Are there alternatives to 2,4,6-Trihydroxyisophthalaldehyde (CAS: 4396-13-8) in synthesis?

There are alternative reagents that can be used in the synthesis of 2,4,6-Trihyd...

4396-13-82,4,6-Trihydroxyisop...
Compound Q&A

What is (2Z)-3-(5-Fluoro-1H-indol-3-yl)-2-sulfanylacrylic acid (CAS: 179461-52-0)?

(2Z)-3-(5-Fluoro-1H-indol-3-yl)-2-sulfanylacrylic acid is a chemical compound wi...

179461-52-0(2Z)-3-(5-Fluoro-1H-...

Source Journal

Chemical Communications

Chemical Communications
CiteScore: 8.6
Self-citation Rate: 4.7%
Articles per Year: 2458

ChemComm publishes urgent research which is of outstanding significance and interest to experts in the field, while also appealing to the journal’s broad chemistry readership. Our communication format is ideally suited to short, urgent studies that are of such importance that they require accelerated publication. Our scope covers all topics in chemistry, and research at the interface of chemistry and other disciplines (such as materials science, nanoscience, physics, engineering and biology) where there is a significant novelty in the chemistry aspects. Major topic areas covered include: Analytical Chemistry Catalysis Chemical Biology and medicinal chemistry Computational Chemistry and Machine Learning Energy and sustainable chemistry Environmental Chemistry Green Chemistry Inorganic Chemistry Materials Chemistry Nanoscience Organic Chemistry Physical Chemistry Polymer Chemistry Supramolecular Chemistry

Recommended Compounds

Recommended Suppliers

Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.