The mechanism of the oxidative addition of aryl halides to Pd-catalysts: a DFT investigation
Literature Information
Publication Date
2004-08-20
DOI
10.1039/B409144B
Impact Factor
6.222
Authors
Lukas J. Gooßen, Debasis Koley, Holger Hermann, Walter Thiel
View Original
Abstract
Based on DFT calculations, a new mechanism for the oxidative addition of aryl halides to Pd-catalysts is presented. The key intermediate is an anionic Pd-species in which the aryl halide coordinates to the palladium via the halide atom.
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Source Journal
Chemical Communications
CiteScore:
8.6
Self-citation Rate:
4.7%
Articles per Year:
2458
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