New reactions in water: metal-free conversion of alcohols and ketones into α-iodoketones
Literature Information
José Barluenga, María Marco-Arias, Francisco González-Bobes, Alfredo Ballesteros, José M. González
Using water as the reaction medium, ketones can be transformed into α-iodoketones upon treatment with sodium iodide, hydrogen peroxide and an acid; interestingly, α-iodoketones can be also obtained from secondary alcohols through a metal-free tandem oxidation–iodination approach.
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