Electrophilicity parameters for σ-complexation by uncharged electron-deficient aromatic and heteroaromatic structures

Literature Information

Publication Date 2004-09-30
DOI 10.1039/B410356D
Impact Factor 6.222
Authors

François Terrier, Régis Goumont, Taoufik Boubaker, Erwin Buncel


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Abstract

Using appropriate sets of reference nucleophiles, the reactivity of neutral electrophiles of widely different reactivity and structure has been ranked on the comprehensive electrophilicity scale of Mayr (Acc. Chem. Res., 2003, 36, 66), holding promise of a general rationalization of σ-complexation processes and related SNAr substitutions.

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