Triphenylphosphine as phosphorus catalyst for reversible chain-transfer catalyzed polymerization (RTCP)
Literature Information
Publication Date
2013-03-04
DOI
10.1039/C3PY00187C
Impact Factor
5.582
Authors
Liangjiu Bai, Lifen Zhang, Yuan Liu, Xiangqiang Pan, Zhenping Cheng, Xiulin Zhu
View Original
Abstract
Triphenylphosphine (TPP) was used as the catalyst for reversible chain-transfer catalyzed polymerizations (RTCPs) of styrene and methyl methacrylate for the first time. The polymerizations showed the typical features of “living”/controlled radical polymerization, and well-defined polymers with designable molecular weights and narrow molecular weight distributions (Mw/Mn < 1.35) were obtained. In addition, RTCP of styrene using TPP as a novel catalyst not only could be conducted in the presence of a limited amount of air but also did not destroy the controllability over polymerizations.
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Polymer Chemistry
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