Selective production of cyclohexanol and methanol from guaiacol over Ru catalyst combined with MgO
Literature Information
Yoshinao Nakagawa, Momoko Ishikawa, Masazumi Tamura, Keiichi Tomishige
Selective demethoxylation from aqueous guaiacol proceeded over Ru catalysts at relatively lower temperatures (≤433 K). Addition of MgO to the reaction media suppressed the unselective C–O dissociation. Cyclohexanol and methanol were obtained in high yield (>80%). A reaction route is proposed where partially hydrogenated guaiacol is decomposed into methanol and phenol, which is further hydrogenated to cyclohexanol.
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