Syntheses, crystal structures of a series of novel alkali metal or alkaline earth metal phosphites

Literature Information

Publication Date 2013-01-14
DOI 10.1039/C3CE26885C
Impact Factor 3.545
Authors

Jian-Han Zhang, Jun-Ling Song, Fang Kong, Jiang-Gao Mao


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Abstract

A series of new alkali metal and alkali-earth metal phosphites, namely, NaIn3(HPO3)5(H2O)4, AIn(HPO3)2 (A = Rb, Cs) and Ba3M2(HPO3)6 (M = Al, Ga, In), have been synthesized by hydrothermal reactions. Their structures have been determined by single-crystal X-ray diffraction. The structure of NaIn3(HPO3)5(H2O)4 shows a complicated 3D anionic framework based on InO6 octahedra connected by HPO3 tetrahedra via corner-sharing, and the 3D anionic network of NaIn3(HPO3)5(H2O)4 can also be described as a new 3,5-net with a Schläfli symbol of {4.82}{42.6.87}{42.6}3{42.88}{43.62.85}{83}. Both AIn(HPO3)2 (A = Rb, Cs) feature a 2D layer composed by InO6 octahedral and HPO3 tetrahedral units with alkali metal cations filling the interlayer spaces. Ba3M2(HPO3)6 (M = Al, Ga, In) are isomorphous, and their structures feature a 3D anionic framework composed of MO6 (M = Al, Ga, In) octahedra and HPO3 tetrahedra interconnected via corner-sharing. IR and UV-vis spectra and TGA curves of these materials were also measured.

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