Thiol–yne reaction of alkyne-derivatized fatty acids: biobased polyols and cytocompatibility of derived polyurethanes

Literature Information

Publication Date 2012-05-25
DOI 10.1039/C2PY20273E
Impact Factor 5.582
Authors

Rodolfo J. González-Paz, Gerard Lligadas, Juan C. Ronda, Marina Galià, Virginia Cádiz


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Abstract

With the goal of obtaining renewable diols and polyols for polyurethane (PU) technology, the thiol–yne coupling reaction was applied to alkyne-derivatized fatty acids derived from naturally occurring oleic and 10-undecenoic acids. The resulting monomers were then polymerized with 4,4′-methylenebis(phenylisocyanate) to produce the corresponding PUs. The chemical structures and thermal and mechanical properties of the synthesized PUs have been evaluated by FTIR and NMR spectroscopy, DSC, TGA and tensile tests respectively. Moreover, the biocompatibilities of the synthesized PUs with human osteoblast-like cell line (MG63) have also been evaluated for tissue engineering purposes.

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Polymer Chemistry

Polymer Chemistry
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