Coordination polymers based on square planar Co(ii) node and linear spacer: solvent-dependent pseudo-polymorphism and an unprecedented interpenetrating structure containing both 2D and 3D topological isomers
Literature Information
Dong Mok Shin, In Su Lee, Young Keun Chung, Myoung Soo Lah
Reaction of Co(NCS)2 with 1-methyl-1′-(4-pyridyl)-2-(4-pyrimidyl)ethylene (mppe) in different solvents yields two kinds of novel coordination polymer structures of [Co(mppe)2(NCS)2]n: one of them shows an unprecedented interpenetrating structure with both 2D and 3D topological isomers.
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![N-[(1S,2R,4S)-2-Amino-4-(dimethylcarbamoyl)cyclohexyl]-N'-(5-chloro-2-pyridinyl)ethanediamide structure N-[(1S,2R,4S)-2-Amino-4-(dimethylcarbamoyl)cyclohexyl]-N'-(5-chloro-2-pyridinyl)ethanediamide structure](https://static.chemtradehub.com/structs/480/480452-37-7-0898.webp)
